vanadium tetrafluoride
- CAS Registry Number: 10049-16-8
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Ion clustering data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
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Clustering reactions
+ vanadium tetrafluoride = (
• vanadium tetrafluoride)
By formula: F- + vanadium tetrafluoride = (F- • vanadium tetrafluoride)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 365. ± 24. | kJ/mol | TDEq | Kuznetsov, Korobov, et al., 1989 | gas phase; Fluoride Affinity: 14.2±3.9 kcal/mol < UF4 |
| ΔrH° | 363. ± 27. | kJ/mol | TDEq | Sidorov, Boltalina, et al., 1989 | gas phase; value altered from reference due to conversion from electron convention to ion convention |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Kuznetsov, Korobov, et al., 1989
Kuznetsov, S.V.; Korobov, M.V.; Sidorov, L.N.,
Gas-Phase Negative Ion Chemistry of Platinum Metal Fluorides. III. Negative Ions of Pentafluorides.,
Int. J. Mass Spectrom. Ion Proc., 1989, 91, 3, 283, https://doi.org/10.1016/0168-1176(89)80083-7
. [all data]
Sidorov, Boltalina, et al., 1989
Sidorov, L.N.; Boltalina, O.V.; Borschevskii, A.Ya.,
Electron Affinities of Vanadium Fluorides. Additional Experimental Data and Corrections.,
Int. J. Mass Spectrom. Ion Proc., 1989, 87, 2, R1, https://doi.org/10.1016/0168-1176(89)80025-4
. [all data]
Notes
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- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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