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Nitromethane anion


Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Clustering reactions

CH3NO2- + Methane, nitro- = (CH3NO2- bullet Methane, nitro-)

By formula: CH3NO2- + CH3NO2 = (CH3NO2- bullet CH3NO2)

Quantity Value Units Method Reference Comment
Deltar63.60 ± 0.84kJ/molN/ACompton, Carman Jr., et al., 1996gas phase; Shift in electron detachment from non-solvated ion

(CH3NO2- bullet Methane, nitro-) + Methane, nitro- = (CH3NO2- bullet 2Methane, nitro-)

By formula: (CH3NO2- bullet CH3NO2) + CH3NO2 = (CH3NO2- bullet 2CH3NO2)

Quantity Value Units Method Reference Comment
Deltar50. ± 150.kJ/molN/ACompton, Carman Jr., et al., 1996gas phase; shift in electron detachment from less solvated ion
Deltar53.6 ± 1.3kJ/molTDAsWincel, 2003gas phase
Quantity Value Units Method Reference Comment
Deltar24.7kJ/molTDAsWincel, 2003gas phase

References

Go To: Top, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Compton, Carman Jr., et al., 1996
Compton, R.N.; Carman Jr.; Desfrancois, C.; Abdoul-Carmine, H.; Schermann, J.P.; Hendricks, J.H., On the binding of Electrons to Nitromethane: Dipole and Valence Bound Anions, J. Chem. Phys., 1996, 105, 9, 3472, https://doi.org/10.1063/1.472993 . [all data]

Wincel, 2003
Wincel, H., Gas-phase Solvation of Cl-, NO2-, CH2NO2-, CH3NO2-, and CH3NO4- by CH3NO2, Int. J. Mass Spectrom., 2003, 226, 3, 341-353, https://doi.org/10.1016/S1387-3806(03)00066-6 . [all data]


Notes

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