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UF5 anion


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
3.820 ± 0.050LPESDau, Su, et al., 2012anion ground state is triplet. Vertical Detachment Energy = 4.40±0.05 eV
3.47 ± 0.27R-ABoltalina, Borshchevskii, et al., 1992Critical review; value altered from reference due to conversion from electron convention to ion convention
3.97 ± 0.26R-APyatenko, Guasarov, et al., 1984Critical review, other literature data corrected; value altered from reference due to conversion from electron convention to ion convention
3.78 ± 0.40R-APyatenko, Gusarov, et al., 1980value altered from reference due to conversion from electron convention to ion convention
3.71 ± 0.15R-ACompton, 1977From UF6
>4.04 ± 0.35R-AMathur, Rothe, et al., 1977From UF6

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Dau, Su, et al., 2012
Dau, P.D.; Su, J.; Liu, H.T.; Huang, D.L.; Wei, F.; Li, J.; Wang, L.S., Photoelectron spectroscopy and theoretical studies of UF5- and UF6-, J. Chem. Phys., 2012, 136, 19, 194304, https://doi.org/10.1063/1.4716182 . [all data]

Boltalina, Borshchevskii, et al., 1992
Boltalina, O.V.; Borshchevskii, A.Y.; Sidorov, L.N., Thermochemistry of 3d Elements Fluorides and Their Negative Ions in Gas Phase, Russ. J. Phys. Chem., 1992, 66, 1223. [all data]

Pyatenko, Guasarov, et al., 1984
Pyatenko, A.T.; Guasarov, A.V.; Gorokhov, L.N., Thermochemistry of Negative Ions in the U-F System, Russ. J. Phys. Chem., 1984, 58, 1. [all data]

Pyatenko, Gusarov, et al., 1980
Pyatenko, A.T.; Gusarov, A.V.; Gorokhov, L.N., Thermochemical Properties of Negative Ions in Vapor over UF4, High Temp., 1980, 18, 857. [all data]

Compton, 1977
Compton, R.N., On the formation of positive and negative ions in gaseous UF6, J. Chem. Phys., 1977, 66, 4478. [all data]

Mathur, Rothe, et al., 1977
Mathur, B.P.; Rothe, R.W.; Reck, G.P., Ionization reactions of metal hexafluorides with alkali atoms and dimers, J. Chem. Phys., 1977, 67, 377. [all data]


Notes

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