FC(O)N


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   D


 Energy 
 (cm-1
 Med.   Transition   λmin 
 (nm) 
 λmax 
 (nm) 
 References

To = 30900 ± 50 Ne D-X 237 324 Zeng, Beckers, et al., 2011


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 1700 Ne AB Zeng, Beckers, et al., 2011
462 Ne AB Zeng, Beckers, et al., 2011

State:   C


 Energy 
 (cm-1
 Med.   Transition   λmin 
 (nm) 
 λmax 
 (nm) 
 References

To = 29166 ± 50 Ne C-X 332 343 Zeng, Beckers, et al., 2011


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 475 Ne AB Zeng, Beckers, et al., 2011

State:   B


 Energy 
 (cm-1
 Med.   Transition   λmin 
 (nm) 
 λmax 
 (nm) 
 References

To = 25428 ± 50 Ne B-X 351 393 Zeng, Beckers, et al., 2011


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 390 Ne AB Zeng, Beckers, et al., 2011

State:   A


 Energy 
 (cm-1
 Med.   Transition   λmin 
 (nm) 
 λmax 
 (nm) 
 References

To = 13890 ± 50 Ne A-X 506 715 Zeng, Beckers, et al., 2011


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 465 Ne AB Zeng, Beckers, et al., 2011

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 1 CO stretch 1678.1 m s Ne IR Zeng, Beckers, et al., 2011
1 CO stretch 1681.3 s Ar IR Zeng, Beckers, et al., 2011
2 FCN a-stretch 1190.1 vs Ne IR Zeng, Beckers, et al., 2011
2 FCN a-stretch 1193.8 vs Ar IR Zeng, Beckers, et al., 2011
3 FCN s-stretch 879.3 w m Ne IR Zeng, Beckers, et al., 2011
3 FCN s-stretch 879.8 w m Ar IR Zeng, Beckers, et al., 2011
4 FCO bend 586.3 w Ne IR Zeng, Beckers, et al., 2011
4 FCO bend 588.7 w Ar IR Zeng, Beckers, et al., 2011
5 FCN bend 434.8 w Ar IR Zeng, Beckers, et al., 2011
a 6 OPLA 651.1 w m Ne IR Zeng, Beckers, et al., 2011
6 OPLA 646.5 w m Ar IR Zeng, Beckers, et al., 2011

Notes

wWeak
mMedium
sStrong
vsVery strong
oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Zeng, Beckers, et al., 2011
Zeng, X.; Beckers, H.; Willner, H.; Grote, D.; Sander, W., The Missing Link: Triplet Fluorocarbonyl Nitrene FC(O)N, Chem. Eur. J., 2011, 17, 14, 3977, https://doi.org/10.1002/chem.201002955 . [all data]


Notes

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