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Dichlorine dioxide


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Tx = 40800 gas Cox and Hayman, 1988
Burkholder, Orlando, et al., 1990
DeMore and Tschuikow-Roux, 1990
Molina, Colussi, et al., 1990
Huder and DeMore, 1995
Pope, Hansen, et al., 2007
von Hobe, Stroh, et al., 2009
Chen, Lien, et al., 2009

State:   ?


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Tx = 40800 gas Papanastasiou, Papadimitriou, et al., 2009
Wilmouth, Hanisco, et al., 2009
Jin, Chen, et al., 2010

State:   ?


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Td = 27800 L Ar Jacobs, Kronberg, et al., 1994

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a 1 OO stretch 750 gas IR Burkholder, Orlando, et al., 1990
Brust, Zabel, et al., 1997
1 OO stretch 755.0 w m Ne IR von Hobe, Stroh, et al., 2009
1 OO stretch 754.0 m Ar IR Cheng and Lee, 1989
Jacobs, Kronberg, et al., 1994
2 ClO s-stretch 560 gas IR Burkholder, Orlando, et al., 1990
2 ClO s-stretch 558.6 m Ne IR von Hobe, Stroh, et al., 2009
2 ClO s-stretch 543.0 m Ar IR Jacobs, Kronberg, et al., 1994
b 5 ClO a-stretch 653 gas IR Burkholder, Orlando, et al., 1990
Brust, Zabel, et al., 1997
5 ClO a-stretch 652.5 vs Ne IR von Hobe, Stroh, et al., 2009
5 ClO a-stretch 647.7 vs Ar IR Cheng and Lee, 1989
Jacobs, Kronberg, et al., 1994
6 Deformation 418.5 w Ar IR Jacobs, Kronberg, et al., 1994

Additional references: Jacox, 1994, page 225; Jacox, 1998, page 263; Jacox, 2003, page 244; Birk, Friedl, et al., 1989

Notes

wWeak
mMedium
vsVery strong
LLower bound
xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.
dPhotodissociation threshold

References

Go To: Top, Vibrational and/or electronic energy levels, NIST Free Links, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Cox and Hayman, 1988
Cox, R.A.; Hayman, G.D., The stability and photochemistry of dimers of the ClO radical and implications for Antarctic ozone depletion, Nature, 1988, 332, 6167, 796, https://doi.org/10.1038/332796a0 . [all data]

Burkholder, Orlando, et al., 1990
Burkholder, J.B.; Orlando, J.J.; Howard, C.J., Ultraviolet absorption cross sections of chlorine oxide (Cl2O2) between 210 and 410 nm, J. Phys. Chem., 1990, 94, 2, 687, https://doi.org/10.1021/j100365a033 . [all data]

DeMore and Tschuikow-Roux, 1990
DeMore, W.B.; Tschuikow-Roux, E., Ultraviolet spectrum and chemical reactivity of the chlorine monoxide dimer, J. Phys. Chem., 1990, 94, 15, 5856, https://doi.org/10.1021/j100378a046 . [all data]

Molina, Colussi, et al., 1990
Molina, M.J.; Colussi, A.J.; Molina, L.T.; Schindler, R.N.; Tso, T.-L., Quantum yield of chlorine-atom formation in the photodissociation of chlorine peroxide (ClOOCl) at 308 nm, Chem. Phys. Lett., 1990, 173, 4, 310, https://doi.org/10.1016/0009-2614(90)85275-H . [all data]

Huder and DeMore, 1995
Huder, K.J.; DeMore, W.B., Absorption cross sections of the ClO dimer, J. Phys. Chem., 1995, 99, 12, 3905, https://doi.org/10.1021/j100012a007 . [all data]

Pope, Hansen, et al., 2007
Pope, F.D.; Hansen, J.C.; Bayes, K.D.; Friedl, R.R.; Sander, S.P., Ultraviolet Absorption Spectrum of Chlorine Peroxide, ClOOCl, J. Phys. Chem. A, 2007, 111, 20, 4322, https://doi.org/10.1021/jp067660w . [all data]

von Hobe, Stroh, et al., 2009
von Hobe, M.; Stroh, F.; Beckers, H.; Benter, T.; Willner, H., The UV/Vis absorption spectrum of matrix-isolated dichlorine peroxide, ClOOCl, Phys. Chem. Chem. Phys., 2009, 11, 10, 1571, https://doi.org/10.1039/b814373k . [all data]

Chen, Lien, et al., 2009
Chen, H.-Y.; Lien, C.-Y.; Lin, W.-Y.; Lee, Y.T.; Lin, J.J., UV Absorption Cross Sections of ClOOCl Are Consistent with Ozone Degradation Models, Science, 2009, 324, 5928, 781, https://doi.org/10.1126/science.1171305 . [all data]

Papanastasiou, Papadimitriou, et al., 2009
Papanastasiou, D.K.; Papadimitriou, V.C.; Fahey, D.W.; Burkholder, J.B., UV Absorption Spectrum of the ClO Dimer (Cl, J. Phys. Chem. A, 2009, 113, 49, 13711, https://doi.org/10.1021/jp9065345 . [all data]

Wilmouth, Hanisco, et al., 2009
Wilmouth, D.M.; Hanisco, T.F.; Stimpfle, R.M.; Anderson, J.G., Chlorine-Catalyzed Ozone Destruction: Cl Atom Production from ClOOCl Photolysis, J. Phys. Chem. A, 2009, 113, 51, 14099, https://doi.org/10.1021/jp9053204 . [all data]

Jin, Chen, et al., 2010
Jin, B.; Chen, I.-C.; Huang, W.-T.; Lien, C.-Y.; Guchhait, N.; Lin, J.J., Photodissociation Cross Section of ClOOCl at 330 nm, J. Phys. Chem. A, 2010, 114, 14, 4791, https://doi.org/10.1021/jp909374k . [all data]

Jacobs, Kronberg, et al., 1994
Jacobs, J.; Kronberg, M.; Muller, H.S.P.; Willner, H., An Experimental Study on the Photochemistry and Vibrational Spectroscopy of Three Isomers of Cl2O2 Isolated in Cryogenic Matrixes, J. Am. Chem. Soc., 1994, 116, 3, 1106, https://doi.org/10.1021/ja00082a038 . [all data]

Brust, Zabel, et al., 1997
Brust, A.S.; Zabel, F.; Becker, K.H., Integrated IR band intensities of the, Geophys. Res. Lett., 1997, 24, 11, 1395, https://doi.org/10.1029/97GL01273 . [all data]

Cheng and Lee, 1989
Cheng, B.-M.; Lee, Y.-P., Production and trapping of gaseous dimeric ClO: The infrared spectrum of chlorine peroxide (ClOOCl) in solid argon, J. Chem. Phys., 1989, 90, 11, 5930, https://doi.org/10.1063/1.456359 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Birk, Friedl, et al., 1989
Birk, M.; Friedl, R.R.; Cohen, E.A.; Pickett, H.M.; Sander, S.P., The rotational spectrum and structure of chlorine peroxide, J. Chem. Phys., 1989, 91, 11, 6588, https://doi.org/10.1063/1.457377 . [all data]


Notes

Go To: Top, Vibrational and/or electronic energy levels, NIST Free Links, References