tetrakis(methylethylamino)zirconium (IV)


Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Enthalpy of sublimation

ΔsubH (kJ/mol) Temperature (K) Method Reference Comment
79.4 ± 2.4278. - 333.MEMonnier, Nuta, et al., 2009Authors state in the paper that the compound is a liquid at room temperature. Figure 3 in the paper shows that the plot of ln P versus 1/T is linear over the entire temperature range. The authors refer to the enthalpy as the enthalpy of sublimation. We have taken the value to be the enthalpy of vaporization given the authors’ statement that the compound is a liquid. The compound’s melting point temperature is unknown.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Monnier, Nuta, et al., 2009
Monnier, D.; Nuta, I.; Chatillon, C.; Gros-Jean, M.; Volpi, F.; Blanquet, E., Gaseous Phase Study of the Zr-Organometallic ALD Precursor TEMAZ by Mass Spectrometry, J. Electrochem. Soc., 2009, 156, 1, H71, https://doi.org/10.1149/1.3009595 . [all data]


Notes

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