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(Me2N)2C=C(NMe2)2..Al anion


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
0.70 ± 0.20LPESLi, Grubisic, et al., 2009Vertical Detachment Energy: 1.1±0.1 eV. Likely Al- insertion into a C-N bond, not a loose cluster

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Li, Grubisic, et al., 2009
Li, X.; Grubisic, A.; Eustis, S.; Wang, D.; Lectka, T.; Gantefor, G.F.; Bowen, K.H.; Burgert, R.; Schnockel, H., The reaction of aluminum cluster anions with tetrakis(dimethylamino)ethylene (TDMAE): Insertion of an aluminum anion into a C-N bond, Chem. Phys. Lett., 2009, 481, 4-6, 190-193, https://doi.org/10.1016/j.cplett.2009.09.101 . [all data]


Notes

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