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Cyclohexanone, oxime

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Tboil481.2KN/AWeast and Grasselli, 1989BS
Quantity Value Units Method Reference Comment
Tfus362.KN/AWhite and Bishop, 1940Uncertainty assigned by TRC = 4. K; TRC
Quantity Value Units Method Reference Comment
Ttriple362.5KN/AKozyro, Kabo, et al., 1992Crystal phase 1 phase; Uncertainty assigned by TRC = 0.3 K; TRC
Ttriple362.5KN/AKozyro, Sheiman, et al., 1991Crystal phase 1 phase; Uncertainty assigned by TRC = 0.5 K; TRC
Quantity Value Units Method Reference Comment
Deltavap63.1 ± 1.0kJ/molN/ASteele, Chirico, et al., 2002Based on data from 370. - 385. K.; AC
Quantity Value Units Method Reference Comment
Deltasub79.0 ± 2.0kJ/molN/ASteele, Chirico, et al., 2002AC
Deltasub78.32 ± 0.30kJ/molVKozyro, Kabo, et al., 1992see Kozyro, Marachuk, et al., 1989; ALS

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
58.660367.8N/AKozyro, Kabo, et al., 1992DH
58.7 ± 0.6368.CKozyro, Kabo, et al., 1992AC
59.5 ± 0.5371. - 446.N/AKozyro, Kabo, et al., 1992AC

Enthalpy of sublimation

DeltasubH (kJ/mol) Temperature (K) Method Reference Comment
76.5 ± 1.0378.N/ASteele, Chirico, et al., 2002AC
74.0 ± 0.3354.CKozyro, Kabo, et al., 1992AC
79.9 ± 0.7317.MEKozyro, Kabo, et al., 1992Based on data from 288. - 348. K.; AC

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Reference Comment
12.45362.2Zaitsau, Paulechka, et al., 2008AC
12.7362.5Steele, Chirico, et al., 2002AC
12.7362.6Kozyro, Kabo, et al., 1992AC

Enthalpy of phase transition

DeltaHtrs (kJ/mol) Temperature (K) Initial Phase Final Phase Reference Comment
0.0140240.8crystaline, IIIcrystaline, IIKozyro, Kabo, et al., 1992DH
0.0937273.4crystaline, IIcrystaline, IKozyro, Kabo, et al., 1992DH
12.700362.5crystaline, IliquidKozyro, Kabo, et al., 1992DH
74.010353.7crystaline, I Kozyro, Kabo, et al., 1992DH
0.0140240.8crystaline, IIIcrystaline, IIKozyro, Sheiman, et al., 1991, 2DH
0.0937273.4crystaline, IIcrystaline, IKozyro, Sheiman, et al., 1991, 2DH
12.700362.5crystaline, IliquidKozyro, Sheiman, et al., 1991, 2DH

Entropy of phase transition

DeltaStrs (J/mol*K) Temperature (K) Initial Phase Final Phase Reference Comment
0.06240.8crystaline, IIIcrystaline, IIKozyro, Kabo, et al., 1992DH
0.34273.4crystaline, IIcrystaline, IKozyro, Kabo, et al., 1992DH
0.06240.8crystaline, IIIcrystaline, IIKozyro, Sheiman, et al., 1991, 2DH
0.34273.4crystaline, IIcrystaline, IKozyro, Sheiman, et al., 1991, 2DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

White and Bishop, 1940
White, A.H.; Bishop, W.S., Dielectric Evidence of Molecular Rotation in the Crystals of Certain Non-aromatic Compounds, J. Am. Chem. Soc., 1940, 62, 8-16. [all data]

Kozyro, Kabo, et al., 1992
Kozyro, A.A.; Kabo, G.J.; Krouk, V.S.; Sheiman, M.S.; Yursha, I.A.; Simirsky, V.V.; Krasulin, A.P.; Sevruk, V.M.; Gogolinsky, V.I., Thermodynamic properties of cyclohexanone oxime, J. Chem. Thermodyn., 1992, 24, 883-895. [all data]

Kozyro, Sheiman, et al., 1991
Kozyro, A.A.; Sheiman, M.S.; Kabo, G.Ya.; Yursha, I.A.; Krouk, V.S., Heat capacity and thermodynamic properties of cyclohexanone oxime, Zh. Prikl. Khim. (S.-Peterburg), 1991, 64, 1704-9. [all data]

Steele, Chirico, et al., 2002
Steele, W.V.; Chirico, R.D.; Cowell, A.B.; Knipmeyer, S.E.; Nguyen, A., Thermodynamic Properties and Ideal-Gas Enthalpies of Formation for 1,4-Diisopropylbenzene, 1,2,4,5-Tetraisopropylbenzene, Cyclohexanone Oxime, Dimethyl Malonate, Glutaric Acid, and Pimelic Acid, J. Chem. Eng. Data, 2002, 47, 4, 725-739, https://doi.org/10.1021/je010088b . [all data]

Kozyro, Marachuk, et al., 1989
Kozyro, A.A.; Marachuk, L.I.; Krasulin, A.P.; Yursha, I.A.; Kabo, G.Ya., Thermodynamic properties of cyclohexanone oxime and «epsilon»-caprolactam, J. Appl. Chem. USSR, 1989, 62, 547-550. [all data]

Zaitsau, Paulechka, et al., 2008
Zaitsau, Dzmitry H.; Paulechka, Yauheni U.; Kabo, Gennady J.; Blokhin, Andrey V.; Emel'yanenko, Vladimir N.; Verevkin, Sergey P.; Heintz, Andreas, Thermodynamics of Cyclohexanone Oxime, J. Chem. Eng. Data, 2008, 53, 3, 694-703, https://doi.org/10.1021/je700546r . [all data]

Kozyro, Sheiman, et al., 1991, 2
Kozyro, A.A.; Sheiman, M.S.; Kabo, G.Ya.; Yursha, I.A.; Kruk, V.S., Heat capacity and thermodynamic properties of cyclohexanone oxime, Zh. Prikl. Khim. (Leningrad), 1991, 64(8), 1704-1709. [all data]


Notes

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