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cyclohexyl isocyanide


Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
CAL - James S. Chickos, William E. Acree, Jr., Joel F. Liebman, Students of Chem 202 (Introduction to the Literature of Chemistry), University of Missouri -- St. Louis
DH - Eugene S. Domalski and Elizabeth D. Hearing

Enthalpy of fusion

DeltafusH (kcal/mol) Temperature (K) Method Reference Comment
0.951277.7DSCSingh and Murthy, 2008AC
1.01279.6N/ADomalski and Hearing, 1996AC

Entropy of fusion

DeltafusS (cal/mol*K) Temperature (K) Reference Comment
7.665192.6Domalski and Hearing, 1996CAL
3.614279.6

Enthalpy of phase transition

DeltaHtrs (kcal/mol) Temperature (K) Initial Phase Final Phase Reference Comment
1.476192.6crystaline, IIcrystaline, IKishimoto, Pinvidic, et al., 1991DH
1.010279.6crystaline, IliquidKishimoto, Pinvidic, et al., 1991DH

Entropy of phase transition

DeltaStrs (cal/mol*K) Temperature (K) Initial Phase Final Phase Reference Comment
7.665192.6crystaline, IIcrystaline, IKishimoto, Pinvidic, et al., 1991DH
3.614279.6crystaline, IliquidKishimoto, Pinvidic, et al., 1991DH

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
10.72 ± 0.05EIDistefano, Innorta, et al., 1968RDSH
11.0PEYoung and Cheng, 1976Vertical value; LLK

References

Go To: Top, Phase change data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Singh and Murthy, 2008
Singh, L.P.; Murthy, S.S.N., Study of secondary relaxation in disordered plastic crystals of isocyanocyclohexane, cyanocyclohexane, and 1-cyanoadamantane, J. Chem. Phys., 2008, 129, 9, 094501, https://doi.org/10.1063/1.2961036 . [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]

Kishimoto, Pinvidic, et al., 1991
Kishimoto, I.; Pinvidic, J.J.; Matsuo, T.; Suga, H., Phase transition and glass transitions in isocyanocyclohexane studied by a polaro-calorimeter, Proc. Jpn. Acad., Ser, 1991, B 67(4), 66-71. [all data]

Distefano, Innorta, et al., 1968
Distefano, G.; Innorta, G.; Pignataro, S.; Foffani, A., Correlation between the ionization potentials of transition metal complexes and of the corresponding ligands, J. Organometal. Chem., 1968, 14, 165. [all data]

Young and Cheng, 1976
Young, V.Y.; Cheng, K.L., The ultraviolet photoelectron spectra of aliphatic aromatic isonitriles, J. Electron Spectrosc. Relat. Phenom., 1976, 9, 317. [all data]


Notes

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