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1,2,3-triazolide anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C2H2N3- + Hydrogen cation = 1H-1,2,3-Triazole

By formula: C2H2N3- + H+ = C2H3N3

Quantity Value Units Method Reference Comment
Deltar346.4 ± 2.1kcal/molG+TSCatalan, Claramunt, et al., 1988gas phase; The authors state the acidity is for the 2H isomer, which is more stable(G3MP2B3)in the gas phase than the 1H isomer by 3 kcal/mol. However, only the 1H isomer is commercially available; thus, this may not be a clean equilibrium.
Quantity Value Units Method Reference Comment
Deltar339.1 ± 2.0kcal/molIMRECatalan, Claramunt, et al., 1988gas phase; The authors state the acidity is for the 2H isomer, which is more stable(G3MP2B3)in the gas phase than the 1H isomer by 3 kcal/mol. However, only the 1H isomer is commercially available; thus, this may not be a clean equilibrium.

Gas phase ion energetics data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
3.4470 ± 0.0040LPESIchino, Andrews, et al., 2008 

Protonation reactions

C2H2N3- + Hydrogen cation = 1H-1,2,3-Triazole

By formula: C2H2N3- + H+ = C2H3N3

Quantity Value Units Method Reference Comment
Deltar346.4 ± 2.1kcal/molG+TSCatalan, Claramunt, et al., 1988gas phase; The authors state the acidity is for the 2H isomer, which is more stable(G3MP2B3)in the gas phase than the 1H isomer by 3 kcal/mol. However, only the 1H isomer is commercially available; thus, this may not be a clean equilibrium.
Quantity Value Units Method Reference Comment
Deltar339.1 ± 2.0kcal/molIMRECatalan, Claramunt, et al., 1988gas phase; The authors state the acidity is for the 2H isomer, which is more stable(G3MP2B3)in the gas phase than the 1H isomer by 3 kcal/mol. However, only the 1H isomer is commercially available; thus, this may not be a clean equilibrium.

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Catalan, Claramunt, et al., 1988
Catalan, J.; Claramunt, R.M.; Elguero, J.; Menedez, M.; Anvia, F.; Quian, J.H.; Taagepera, M.; Taft, R.W., Basicity and Acidity of Azoles. The Annelation Effect in Azoles., J. Am. Chem. Soc., 1988, 110, 13, 4107, https://doi.org/10.1021/ja00221a001 . [all data]

Ichino, Andrews, et al., 2008
Ichino, T.; Andrews, D.H.; Rathbone, G.J.; Misaizu, F.; Calvi, R.M.D.; Wren, S.W.; Kato, S.; Bierbaum, V.M.; Lineberger, W.C., Ion chemistry of 1H-1,2,3-Triazole, J. Phys. Chem. B, 2008, 112, 2, 545-557, https://doi.org/10.1021/jp074824f . [all data]


Notes

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