Diethyl sulfide

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfgas-83.5 ± 2.3kJ/molCcbVoronkov, Klyuchnikov, et al., 1989 
Δfgas-82.72 ± 0.79kJ/molCcrHubbard, Good, et al., 1958see Hubbard, Katz, et al., 1954

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfliquid-119.3 ± 2.0kJ/molCcbVoronkov, Klyuchnikov, et al., 1989ALS
Δfliquid-119.4 ± 0.84kJ/molCcrHubbard, Good, et al., 1958Reanalyzed by Cox and Pilcher, 1970, Original value = -118.6 ± 0.79 kJ/mol; see Hubbard, Katz, et al., 1954; ALS
Quantity Value Units Method Reference Comment
Δcliquid-3486.1 ± 0.67kJ/molCcrHubbard, Good, et al., 1958Reanalyzed by Cox and Pilcher, 1970, Original value = -3485.4 ± 0.67 kJ/mol; see Hubbard, Katz, et al., 1954; ALS
Δcliquid-3471.kJ/molCcbBerthelot, 1901ALS
Quantity Value Units Method Reference Comment
liquid269.28J/mol*KN/AScott, Finke, et al., 1952DH

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
171.42298.15Scott, Finke, et al., 1952T = 16 to 316 K.; DH

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C4H10S+ + Diethyl sulfide = (C4H10S+ • Diethyl sulfide)

By formula: C4H10S+ + C4H10S = (C4H10S+ • C4H10S)

Bond type: Charge transfer bond (positive ion)

Quantity Value Units Method Reference Comment
Δr104.kJ/molDTJames, McKee, et al., 1996gas phase; ΔrH(0K) = 107. kJ/mol
Δr112.kJ/molDTDeng, Illies, et al., 1995gas phase; ΔrH(0K) = 120. kJ/mol
Quantity Value Units Method Reference Comment
Δr118.J/mol*KDTJames, McKee, et al., 1996gas phase; ΔrH(0K) = 107. kJ/mol
Δr143.J/mol*KDTDeng, Illies, et al., 1995gas phase; ΔrH(0K) = 120. kJ/mol

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Voronkov, Klyuchnikov, et al., 1989
Voronkov, M.G.; Klyuchnikov, V.A.; Kolabin, S.N.; Shvets, G.N.; Varusin, P.I.; Deryagina, E.N.; Korchevin, N.A.; Tsvetnitskaya, S.I., Thermochemical properties of diorganyl chalcogenides and dichalcogenides RMnR(M = S, Se, Te; n = 1, 2)., Dokl. Phys. Chem. (Engl. Transl.), 1989, 307, 650-653, In original 1139. [all data]

Hubbard, Good, et al., 1958
Hubbard, W.N.; Good, W.D.; Waddington, G., The heats of combustion, formation and isomerization of the seven isomeric C4H10S alkane thiols and sulfides, J. Phys. Chem., 1958, 62, 614-617. [all data]

Hubbard, Katz, et al., 1954
Hubbard, W.N.; Katz, C.; Waddington, G., A rotating combustion bomb for precision calorimetry. Heats of combustion of some sulfur-containing compounds, J. Phys. Chem., 1954, 58, 142. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Berthelot, 1901
Berthelot, M., Chimie Organique. - Nouvelles recherches sur l'isomerie des ethers sulfocyaniques, Compt. Rend., 1901, 132, 57-58. [all data]

Scott, Finke, et al., 1952
Scott, D.W.; Finke, H.L.; Hubbard, W.N.; McCullough, J.P.; Oliver, G.D.; Gross, M.E.; Katz, C.; Williamson, K.D.; Waddington, G.; Huffman, H.M., 3-Thiapentane: heat capacity, heats of fusion and vaporization, vapor pressure, entropy, heat of formation and thermodynamic functions, J. Am. Chem. Soc., 1952, 74, 4656-4662. [all data]

James, McKee, et al., 1996
James, M.A.; McKee, M.L.; Illies, A.J., Gas-phase bond strength and atomic connectivity studies of the unsymmetrical two-center three-electron ion, [Et2S...SMe2]+, J. Am. Chem. Soc., 1996, 118, 33, 7836, https://doi.org/10.1021/ja960455h . [all data]

Deng, Illies, et al., 1995
Deng, Y.; Illies, A.J.; James, M.A.; McKee, M.L.; Peschke, M., A Definitive Investigation of the Gas-Phase Two-Center Three-electron Bond in [H2S:SH2+], [Me2S:SMe2]+, and [Et2S:SEt2]+: Therory and Experiment, J. Am. Chem. Soc., 1995, 117, 1, 420, https://doi.org/10.1021/ja00106a048 . [all data]


Notes

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