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Boron oxide anion


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
gas,1 bar215.92J/mol*KReviewChase, 1998Data last reviewed in December, 1968

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

BO2- + Hydrogen cation = HBO2

By formula: BO2- + H+ = HBO2

Quantity Value Units Method Reference Comment
Deltar1351. ± 23.kJ/molD-EAZhai, Wang, et al., 2007gas phase
Deltar1356. ± 26.kJ/molD-EASidorov, Rudnyi, et al., 1983gas phase; value altered from reference due to conversion from electron convention to ion convention

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

BO2- + Hydrogen cation = HBO2

By formula: BO2- + H+ = HBO2

Quantity Value Units Method Reference Comment
Deltar1351. ± 23.kJ/molD-EAZhai, Wang, et al., 2007gas phase
Deltar1356. ± 26.kJ/molD-EASidorov, Rudnyi, et al., 1983gas phase; value altered from reference due to conversion from electron convention to ion convention

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Td = 35985 ± 240 gas Zhai, Wang, et al., 2007, 2

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

Piu 2 Bend 587.8 Ar IR Burkholder and Andrews, 1991
Sigmau+ 3 Asym. stretch 1931.0 Ar IR Burkholder and Andrews, 1991
3 Asym. stretch 1926.1 Kr IR Burkholder and Andrews, 1991
3 Asym. stretch 1915.6 Xe IR Burkholder and Andrews, 1991
3 Asym. stretch 1925.8 O2 IR Burkholder and Andrews, 1991

Additional references: Jacox, 1994, page 84

Notes

dPhotodissociation threshold

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Zhai, Wang, et al., 2007
Zhai, H.J.; Wang, L.M.; Li, S.D.; Wang, L.S., Vibrationally resolved photoelectron spectroscopy of BO- and BO2-: A joint experimental and theoretical study, J. Phys. Chem. A, 2007, 111, 6, 1030-1035, https://doi.org/10.1021/jp0666939 . [all data]

Sidorov, Rudnyi, et al., 1983
Sidorov, L.N.; Rudnyi, E.B.; Nikitin, M.I.; Sorokin, I.D., Gas Phase Anion Exchange Reactions and the Determination of the Heats of Formation of Metaphosphate (PO3-), metaborate (BO2-), and perrhennate (ReO4-), Dokl. Akad. Nauk SSSR Ser. Khim., 1983, 272, 1172. [all data]

Zhai, Wang, et al., 2007, 2
Zhai, H.-J.; Wang, L.-M.; Li, S.-D.; Wang, L.-S., Vibrationally Resolved Photoelectron Spectroscopy of BO, J. Phys. Chem. A, 2007, 111, 6, 1030, https://doi.org/10.1021/jp0666939 . [all data]

Burkholder and Andrews, 1991
Burkholder, T.R.; Andrews, L., Reactions of boron atoms with molecular oxygen. Infrared spectra of BO, BO2, B2O2, B2O3, and BO-2 in solid argon, J. Chem. Phys., 1991, 95, 12, 8697, https://doi.org/10.1063/1.461814 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]


Notes

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