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CH2CHCH2+


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 1 CH2 s-stretch 3112 A gas PF Douberly, Ricks, et al., 2008
1 CH2 s-stretch 3113 gas PF Douberly, Ricks, et al., 2008
7 C3 bend 436 ± 2 gas PE Houle and Beauchamp, 1978
Schussler, Deyerl, et al., 2003
Xing, Reed, et al., 2007
Gasser, Schulenburg, et al., 2009
a2 9 CH2 a-twist 603 ± 2 gas TPE Gasser, Schulenburg, et al., 2009
b1 10 CH OPLA 1009 ± 2 gas TPE Gasser, Schulenburg, et al., 2009
10 CH OPLA 1025 gas PF Douberly, Ricks, et al., 2008
11 CH2 OPLA 1111 ± 2 gas TPE Gasser, Schulenburg, et al., 2009
11 CH2 OPLA 1136 A gas PF Douberly, Ricks, et al., 2008
11 CH2 OPLA 1130 gas PF Douberly, Ricks, et al., 2008
12 CH2 s-twist 283 ± 2 gas TPE Gasser, Schulenburg, et al., 2009
b2 15 CH2 scissor 1581 A gas PF Douberly, Ricks, et al., 2008
15 CH2 scissor 1585 gas PF Douberly, Ricks, et al., 2008
16 CH bend 1418 A gas PF Douberly, Ricks, et al., 2008
16 CH2 scissor 1421 gas PF Douberly, Ricks, et al., 2008
17 C3 a-stretch 1276 ± 2 gas TPE Gasser, Schulenburg, et al., 2009
17 C3 a-stretch 1226 A gas PF Douberly, Ricks, et al., 2008
17 C3 a-stretch 1230 gas PF Douberly, Ricks, et al., 2008

Additional references: Jacox, 1994, page 372; Jacox, 2003, page 350

Notes

A0~1 cm-1 uncertainty

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Douberly, Ricks, et al., 2008
Douberly, G.E.; Ricks, A.M.; Schleyer, P.v.R.; Duncan, M.A., Infrared spectroscopy of gas phase C[sub 3]H[sub 5]+]: The allyl and 2-propenyl cations, J. Chem. Phys., 2008, 128, 2, 021102, https://doi.org/10.1063/1.2828553 . [all data]

Houle and Beauchamp, 1978
Houle, F.A.; Beauchamp, J.L., Detection and investigation of allyl and benzyl radicals by photoelectron spectroscopy, J. Am. Chem. Soc., 1978, 100, 3290. [all data]

Schussler, Deyerl, et al., 2003
Schussler, T.; Deyerl, H.-J.; Dummler, S.; Fischer, I.; Alcaraz, C.; Elhanine, M., The vacuum ultraviolet photochemistry of the allyl radical investigated using synchrotron radiation, J. Chem. Phys., 2003, 118, 20, 9077, https://doi.org/10.1063/1.1576387 . [all data]

Xing, Reed, et al., 2007
Xing, X.; Reed, B.; Lau, K.-C.; Ng, C.Y.; Zhang, X.; Ellison, G.B., Vacuum ultraviolet laser pulsed field ionization-photoelectron study of allyl radical CH[sub 2]CHCH[sub 2], J. Chem. Phys., 2007, 126, 17, 171101, https://doi.org/10.1063/1.2737443 . [all data]

Gasser, Schulenburg, et al., 2009
Gasser, M.; Schulenburg, A.M.; Dietiker, P.M.; Bach, A.; Merkt, F.; Chen, P., Single-photon and resonance-enhanced multiphoton threshold ionization of the allyl radical, J. Chem. Phys., 2009, 131, 1, 014304, https://doi.org/10.1063/1.3157185 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]


Notes

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