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Pyromellitic dianhydride

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafsolid-953.5kJ/molCcbKaryakin, Bazhan, et al., 1977ALS
Deltafsolid-1047.kJ/molCcbBaroody and Carpenter, 1972High level of uncertainty in the data; ALS
Deltafsolid-907.34kJ/molCcbMullayanov, Mukhutdinov, et al., 1967ALS
Quantity Value Units Method Reference Comment
Deltacsolid-3267. ± 1.kJ/molCcbKaryakin, Bazhan, et al., 1977Corresponding «DELTA»fsolid = -953.5 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacsolid-3312.7 ± 9.1kJ/molCcbMullayanov, Mukhutdinov, et al., 1967Corresponding «DELTA»fsolid = -908.22 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Quantity Value Units Method Reference Comment
solid,1 bar237.1J/mol*KN/ADunn, Rahman, et al., 1978DH
solid,1 bar236.5J/mol*KN/AKaryakin, Mochalov, et al., 1973DH
solid,1 bar242.1J/mol*KN/AKaryakin, Bazhan, et al., 1977, 2DH

Constant pressure heat capacity of solid

Cp,solid (J/mol*K) Temperature (K) Reference Comment
215.7298.15Dunn, Rahman, et al., 1978T = 5 to 300 K.; DH
231.4298.15Marchidan and Ciopec, 1978T = 298 to 580 K.; DH
219.9300.Karyakin, Bazhan, et al., 1977, 2T = 60 to 400 K.; DH
219.9300.Karyakin, Mochalov, et al., 1973T = 20 to 300 K.; DH

References

Go To: Top, Condensed phase thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Karyakin, Bazhan, et al., 1977
Karyakin, N.V.; Bazhan, N.G.; Sapozhnikov, V.N.; Shvetsova, K.G.; Berestneva, G.L.; Lomteva, A.N.; Zimin, Yu.B.; Korshak, V.V., Thermodynamics of synthesis of poly-(p,p'-diphenyleneoxide)pyromellitimide, Polym. Sci. USSR, 1977, 19, 1766-1775. [all data]

Baroody and Carpenter, 1972
Baroody, E.E.; Carpenter, G.A., Heats of formation of propellant compounds (U), Rpt. Naval Ordnance Systems Command Task No. 331-003/067-1/UR2402-001 for Naval Ordance Station, Indian Head, MD, 1972, 1-9. [all data]

Mullayanov, Mukhutdinov, et al., 1967
Mullayanov, F.I.; Mukhutdinov, R.Kh.; Mazitov, M.F.; Buz'ko, M.F.; Borshchenko, V.P.; Krashennikova, V.N., Some properties of pyromellitic dianhydride, Khim. Prom. (Moscow), 1967, 43, 505-506. [all data]

Dunn, Rahman, et al., 1978
Dunn, A.G.; Rahman, A.; Staveley, L.A.K., The heat capacity of pyromellitic dianhydride and of its 1-1 charge-transfer complex with pyrene, J. Chem. Thermodynam., 1978, 10, 787-796. [all data]

Karyakin, Mochalov, et al., 1973
Karyakin, N.V.; Mochalov, A.N.; Kunyevskaya, S.G.; Aron, B.M.; Rabinovich, I.B., Low temperature specific heat of tetracarboxylic acid dianhydrides, Tr. Khim. Khim. Tekhnol, 1973, (1), 60-61. [all data]

Karyakin, Bazhan, et al., 1977, 2
Karyakin, N.V.; Bazhan, N.G.; Sapozhnikov, V.N.; Shvetsova, K.G.; Berestneva, G.L.; Lomteva, A.N.; Zimin, Yu.B.; Korshak, V.V., Thermodynamics of synthesis of poly-(p,p'-diphenylene oxide)pyromellitimide, Vysokomol. Soedin., 1977, A19, 1541-1548. [all data]

Marchidan and Ciopec, 1978
Marchidan, D.I.; Ciopec, M., Thermodynamic properties of maleic, trimellitic and pyromellitic anhydrides, Rev. Roum. Chim., 1978, 23, 19-29. [all data]


Notes

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