Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

NOTICE: Due to scheduled maintenance at our Gaithersburg campus, this site will not be available from 5:00 pm EDT (21:00 UTC) on Friday October 25 until 5:00 pm (21:00 UTC) on Sunday October 27. We apologize for any inconvenience this outage may cause.

tert-C4H9+


Vibrational and/or electronic energy levels

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

CH a-stretch 3036 A gas PF Douberly, Ricks, et al., 2007
CH a-stretch 2965 A gas PF Douberly, Ricks, et al., 2007
CH a-stretch 2834 A gas PF Douberly, Ricks, et al., 2007
1476 A gas PF Douberly, Ricks, et al., 2007
1465 A gas PF Douberly, Ricks, et al., 2007
1410 A gas PF Douberly, Ricks, et al., 2007
1316 A gas PF Douberly, Ricks, et al., 2007
1302 A gas PF Douberly, Ricks, et al., 2007
1278 A gas PF Douberly, Ricks, et al., 2007
1098 A gas PF Douberly, Ricks, et al., 2007
970 A gas PF Douberly, Ricks, et al., 2007
C-C s-stretch 760 ± 30 gas PE Koenig, Balle, et al., 1975
Dyke, Jonathan, et al., 1977
C4 OPLA 460 ± 30 gas PE Koenig, Balle, et al., 1975
Dyke, Jonathan, et al., 1977
Houle and Beauchamp, 1979

Additional references: Jacox, 1994, page 384

Notes

A0~1 cm-1 uncertainty

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Douberly, Ricks, et al., 2007
Douberly, G.E.; Ricks, A.M.; Ticknor, B.W.; Schleyer, P.v.R.; Duncan, M.A., Infrared Spectroscopy of the, J. Am. Chem. Soc., 2007, 129, 45, 13782, https://doi.org/10.1021/ja0753593 . [all data]

Koenig, Balle, et al., 1975
Koenig, T.; Balle, T.; Snell, W., Helium(I) photoelectron spectra of organic radicals, J. Am. Chem. Soc., 1975, 97, 662. [all data]

Dyke, Jonathan, et al., 1977
Dyke, J.; Jonathan, N.; Lee, E.; Morris, A.; Winter, M., Vacuum ultraviolet photoelectron spectroscopy of transient species: Part 8, the t-butyl radical, Phys. Scr., 1977, 16, 197. [all data]

Houle and Beauchamp, 1979
Houle, F.A.; Beauchamp, J.L., Photoelectron spectroscopy of methyl, ethyl, isopropyl, and tert-butyl radicals. Implications for the thermochemistry and structures of the radicals and their corresponding carbonium ions, J. Am. Chem. Soc., 1979, 101, 4067. [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]


Notes

Go To: Top, Vibrational and/or electronic energy levels, References