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1,6-Hexanediol

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.

Quantity Value Units Method Reference Comment
Deltafgas-459.4 ± 1.9kJ/molCcrSteele, Chirico, et al., 1991«DELTA»Hfusion = 21.6±1.0 kcal/mol; ALS
Deltafgas-462.1 ± 4.4kJ/molCcbKnauth and Sabbah, 1990see Knauth and Sabbah, 1989; ALS
Deltafgas-253.4kJ/molN/AContineanu, Corlateanu, et al., 1980Value computed using «DELTA»fHsolid° value of -362.2 kj/mol from Contineanu, Corlateanu, et al., 1980 and «DELTA»subH° value of 108.8 kj/mol from Steele, Chirico, et al., 1991.; DRB
Deltafgas-461.1 ± 5.4kJ/molCcbGardner and Hussain, 1972Hfusion=6.1±0.1; ALS

Condensed phase thermochemistry data

Go To: Top, Gas phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafsolid-583.86 ± 0.72kJ/molCcrSteele, Chirico, et al., 1991«DELTA»Hfusion = 21.6±1.0 kcal/mol; ALS
Deltafsolid-574.1 ± 4.4kJ/molCcbKnauth and Sabbah, 1990see Knauth and Sabbah, 1989; ALS
Deltafsolid-362.17kJ/molCcbContineanu, Corlateanu, et al., 1980High level of uncertainty in the data; ALS
Deltafsolid-569.9 ± 5.0kJ/molCcbGardner and Hussain, 1972Hfusion=6.1±0.1; ALS
Quantity Value Units Method Reference Comment
Deltacsolid-3778.01 ± 0.60kJ/molCcrSteele, Chirico, et al., 1991«DELTA»Hfusion = 21.6±1.0 kcal/mol; Corresponding «DELTA»fsolid = -583.86 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacsolid-3787.7 ± 4.4kJ/molCcbKnauth and Sabbah, 1990see Knauth and Sabbah, 1989; Corresponding «DELTA»fsolid = -574.2 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacsolid-3999.8 ± 2.3kJ/molCcbContineanu, Corlateanu, et al., 1980High level of uncertainty in the data; Corresponding «DELTA»fsolid = -362.09 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacsolid-3791.9 ± 4.8kJ/molCcbGardner and Hussain, 1972Hfusion=6.1±0.1; Corresponding «DELTA»fsolid = -569.94 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS

Constant pressure heat capacity of solid

Cp,solid (J/mol*K) Temperature (K) Reference Comment
202.9298.15N/AT = 268 to 413 K. C/R(c) = 0.128T - 13.72 (268 to 315 K); C/R(liq) = 0.1123T - 1.91 (315 to 413 K), R = 8.31451 J/mol*K.; DH

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Steele, Chirico, et al., 1991
Steele, W.V.; Chirico, R.D.; Nguyen, A.; Hossenlopp, I.A.; Smith, N.K., DIPPR PROJECT 871: Determination of ideal-gas enthalpies of formation for key compounds: The 1989 project results, J. Chem. Thermodyn., 1991, 101-134. [all data]

Knauth and Sabbah, 1990
Knauth, P.; Sabbah, R., Energetics of intra- and intermolecular bonds in «omega»-alkanediols. III. Thermochemical study of 1,6-hexanediol, 1,8-octanediol, 1,9-nonanediol, and 1,10-decanediol at 298.15K, Can. J. Chem., 1990, 68, 731-734. [all data]

Knauth and Sabbah, 1989
Knauth, P.; Sabbah, R., Combustion calorimetry on milligram samples of hydroscopic solid substances with a CRMT rocking bomb calorimeter thermochemical study of «omega»-alkanediols at 298.15 K. part II, J. Chem. Thermodyn., 1989, 21, 779-784. [all data]

Contineanu, Corlateanu, et al., 1980
Contineanu, I.; Corlateanu, E.; Hersocovici, J.; Marchidan, D.I., Combustion and formation enthalpies of 1,6-hexanediol and adipic acid, Rev. Chim. (Bucharest), 1980, 31, 763-764. [all data]

Gardner and Hussain, 1972
Gardner, P.J.; Hussain, K.S., The standard enthalpies of formation of some aliphatic diols, J. Chem. Thermodyn., 1972, 4, 819-827. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, References