H2O(HO)

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
H2O a-stretch 3728.4 Ne IR Jacox and Thompson
H2O a-stretch 3743.0 Ar IR Engdahl, Karlstrom, et al., 2003
H2O a-stretch 3736.5 Ar IR Engdahl, Karlstrom, et al., 2003
H2O a-stretch 3718.6 Ar IR Engdahl, Karlstrom, et al., 2003
H2O a-stretch 3711.5 Ar IR Engdahl, Karlstrom, et al., 2003
H2O s-stretch 3662.6 Ne IR Jacox and Thompson
H2O s-stretch 3634.6 Ar IR Engdahl, Karlstrom, et al., 2003
O..HO a-stretch 3472.4 vs Ne IR Jacox and Thompson
O..HO a-stretch 3453.5 Ar IR Cheng, Lee, et al., 1988
Langford, McKinley, et al., 2000
Engdahl, Karlstrom, et al., 2003
H2O scissor 1598.7 Ne IR Jacox and Thompson
H2O scissor 1593.4 Ar IR Engdahl, Karlstrom, et al., 2003

Additional references: Ohshima, Sato, et al., 2005; Brauer, Sedo, et al., 2005

Notes

vsVery strong

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Jacox and Thompson
Jacox, M.E.; Thompson, W.E., J. Phys. Chem. A 117. [all data]

Engdahl, Karlstrom, et al., 2003
Engdahl, A.; Karlstrom, G.; Nelander, B., The water--hydroxyl radical complex: A matrix isolation study, J. Chem. Phys., 2003, 118, 17, 7797, https://doi.org/10.1063/1.1563608 . [all data]

Cheng, Lee, et al., 1988
Cheng, B.-M.; Lee, Y.-P.; Ogilvie, J.F., The infrared absorption spectrum of hydroxyl radicals in solid argon, Chem. Phys. Lett., 1988, 151, 1-2, 109, https://doi.org/10.1016/0009-2614(88)80079-4 . [all data]

Langford, McKinley, et al., 2000
Langford, V.S.; McKinley, A.J.; Quickenden, T.I., Identification of H, J. Am. Chem. Soc., 2000, 122, 51, 12859, https://doi.org/10.1021/ja003337+ . [all data]

Ohshima, Sato, et al., 2005
Ohshima, Y.; Sato, K.; Sumiyoshi, Y.; Endo, Y., Rotational Spectrum and Hydrogen Bonding of the H, J. Am. Chem. Soc., 2005, 127, 4, 1108, https://doi.org/10.1021/ja0442973 . [all data]

Brauer, Sedo, et al., 2005
Brauer, C.S.; Sedo, G.; Grumstrup, E.M.; Leopold, K.R.; Marshall, M.D.; Leung, H.O., Effects of partially quenched orbital angular momentum on the microwave spectrum and magnetic hyperfine splitting in the OH--water complex, Chem. Phys. Lett., 2005, 401, 4-6, 420, https://doi.org/10.1016/j.cplett.2004.11.090 . [all data]

Notes

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