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OUO+


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   A


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 2677.9 T gas Merritt, Han, et al., 2008


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

Sigmag+ 1 Sym. stretch 926.0 gas TPE Merritt, Han, et al., 2008
Piu 2 Bend 135.3 w gas TPE Merritt, Han, et al., 2008

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

Sigmag+ 1 Sym. stretch 921 ± 4 gas TPE Merritt, Han, et al., 2008
Piu 2 Bend 145.5 w gas TPE Merritt, Han, et al., 2008
Sigmau+ 3 Asym. stretch 980.1 Ne IR Zhou, Andrews, et al., 2000
3 Asym. stretch 975.1 A Ne IR Wang, Andrews, et al., 2004
3 Asym. stretch 972.6 K Ne IR Wang, Andrews, et al., 2004
3 Asym. stretch 970.0 Ne IR Wang, Andrews, et al., 2004
3 Asym. stretch 952.3 Ar IR Zhou, Andrews, et al., 2000
3 Asym. stretch 949.4 K Ar IR Wang, Andrews, et al., 2004
3 Asym. stretch 946.0 Ar IR Wang, Andrews, et al., 2004
3 Asym. stretch 940.6 Kr IR Wang, Andrews, et al., 2004
3 Asym. stretch 929.0 Xe IR Wang, Andrews, et al., 2004

Additional references: Jacox, 2003, page 97

Notes

wWeak
TTentative assignment or approximate value
oEnergy separation between the v = 0 levels of the excited and electronic ground states.
KInteraction with potassium
A0~1 cm-1 uncertainty

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Merritt, Han, et al., 2008
Merritt, J.M.; Han, J.; Heaven, M.C., Spectroscopy of the UO[sub 2][sup +] cation and the delayed ionization of UO[sub 2], J. Chem. Phys., 2008, 128, 8, 084304, https://doi.org/10.1063/1.2830260 . [all data]

Zhou, Andrews, et al., 2000
Zhou, M.; Andrews, L.; Ismail, N.; Marsden, C., Infrared Spectra of UO, J. Phys. Chem. A, 2000, 104, 23, 5495, https://doi.org/10.1021/jp000292q . [all data]

Wang, Andrews, et al., 2004
Wang, X.; Andrews, L.; Li, J.; Bursten, B.E., Significant Interactions between Uranium and Noble-Gas Atoms: Coordination of the UO2+ Cation by Ne, Ar, Kr, and Xe Atoms, Angew. Chem. Int. Ed., 2004, 43, 19, 2554, https://doi.org/10.1002/anie.200453790 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]


Notes

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