HCS+
- Formula: CHS+
- Molecular weight: 45.083
- CAS Registry Number: 59348-25-3
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Vibrational and/or electronic energy levels
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: X
| Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
|---|---|---|---|---|---|---|---|
| Σ+ | 1 | CH stretch | 3141.68 | gas | CC | Rosenbaum, Owrutsky, et al., 1985 Rosenbaum, Owrutsky, et al., 1989 | |
| Π | 2 | Bend | 766.45 | gas | DL | Davies and Rothwell, 1985 | |
Additional references: Jacox, 1994, page 38; Jacox, 1998, page 145; Gudeman, Haese, et al., 1984; Bogey, Demuynck, et al., 1984; Tang and Saito, 1995; Margules, Lewen, et al., 2003
References
Go To: Top, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Rosenbaum, Owrutsky, et al., 1985
Rosenbaum, N.H.; Owrutsky, J.C.; Tack, L.M.; Saykally, R.J.,
Measurement of the ν1 vibration-rotation spectrum of the thioformyl ion (HCS+) by velocity modulation laser spectroscopy,
J. Chem. Phys., 1985, 83, 10, 4845, https://doi.org/10.1063/1.449745
. [all data]
Rosenbaum, Owrutsky, et al., 1989
Rosenbaum, N.H.; Owrutsky, J.C.; Saykally, R.J.,
Velocity modulation infrared laser spectroscopy of HCS+: Analysis of hot bands and perturbations,
J. Mol. Spectrosc., 1989, 133, 2, 364, https://doi.org/10.1016/0022-2852(89)90198-7
. [all data]
Davies and Rothwell, 1985
Davies, P.B.; Rothwell, W.J.,
Infrared laser spectroscopy of the ν2 mode of HCS+,
J. Chem. Phys., 1985, 83, 4, 1496, https://doi.org/10.1063/1.449385
. [all data]
Jacox, 1994
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]
Jacox, 1998
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules: supplement A,
J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017
. [all data]
Gudeman, Haese, et al., 1984
Gudeman, C.S.; Haese, N.H.; Piltch, N.D.; Woods, R.C.,
The observation of the J = 1-2 transition of HCS/+/ in a laboratory glow discharge,
Astrophys. Lett., 1984, 246, L47, https://doi.org/10.1086/183550
. [all data]
Bogey, Demuynck, et al., 1984
Bogey, M.; Demuynck, C.; Destombes, J.L.; Lemoine, B.,
Millimeter wave spectrum of HCS+1,
J. Mol. Spectrosc., 1984, 107, 2, 417, https://doi.org/10.1016/0022-2852(84)90019-5
. [all data]
Tang and Saito, 1995
Tang, J.; Saito, S.,
Microwave Spectra of the Isotopomers of HCS[TSUP]+[/TSUP] and Its Substitution Structure,
Astrophys. J., 1995, 451, 2, L93, https://doi.org/10.1086/309694
. [all data]
Margules, Lewen, et al., 2003
Margules, L.; Lewen, F.; Winnewisser, G.; Botschwina, P.; Muller, H.S.P.,
The rotational spectrum up to 1 THz and the molecular structure of thiomethylium, HCS+,
Phys. Chem. Chem. Phys., 2003, 5, 13, 2770, https://doi.org/10.1039/b303260d
. [all data]
Notes
Go To: Top, Vibrational and/or electronic energy levels, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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