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Fullerene-C84

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Enthalpy of sublimation

DeltasubH (kJ/mol) Temperature (K) Method Reference Comment
202. ± 4.0853.MEBoltalina, Markov, et al., 1998Based on data from 658. - 980. K.
210. ± 6.950.TEPiacente, Palchetti, et al., 1997Based on data from 920. - 1190. K.

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
B - John E. Bartmess

Electron affinity determinations

EA (eV) Method Reference Comment
0.615 ± 0.010LPESWang, Woo, et al., 2007D2d isomer; B
0.820 ± 0.010LPESWang, Woo, et al., 2007D2 isomer; B
0.410 ± 0.070LPESEhrler, Weber, et al., 2003Vertical Detachment Energy: 0.750±0.025 eV; B

Ionization energy determinations

IE (eV) Method Reference Comment
7.1DTIBeck, Weis, et al., 1994LL

References

Go To: Top, Phase change data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Boltalina, Markov, et al., 1998
Boltalina, Olga V.; Markov, Vitaliy Yu.; Borschevskii, Andrey Ya.; Davydov, Vladimir Ya.; Sidorov, Lev N.; Bezmelnitsin, Valery N.; Eletskii, Alexander V.; Taylor, Roger, Saturated vapour pressure and enthalpy of sublimation of C84, Mendeleev Communications, 1998, 8, 4, 141-142, https://doi.org/10.1070/MC1998v008n04ABEH000979 . [all data]

Piacente, Palchetti, et al., 1997
Piacente, V.; Palchetti, C.; Gigli, G.; Scardala, P., Preliminary Study on the Vapor Pressure of C 84 Fullerene, J. Phys. Chem. A, 1997, 101, 24, 4303-4304, https://doi.org/10.1021/jp970821z . [all data]

Wang, Woo, et al., 2007
Wang, X.B.; Woo, H.K.; Yang, J.; Kappes, M.M.; Wang, L.S., Photoelectron spectroscopy of singly and doubly charged higher fullerenes at low temperatures: C-76(-), C-78(-), C-84(-) and C-76(2-), C-78(2-), C-84(2-), J. Phys. Chem. C, 2007, 111, 48, 17684-17689, https://doi.org/10.1021/jp0703861 . [all data]

Ehrler, Weber, et al., 2003
Ehrler, O.T.; Weber, J.M.; Furche, F.; Kappes, M.M., Photoelectron spectroscopy of C-84 dianions, Phys. Rev. Lett., 2003, 91, 11, 391-402, https://doi.org/10.1103/PhysRevLett.91.113006 . [all data]

Beck, Weis, et al., 1994
Beck, R.D.; Weis, P.; Brauchle, G.; Kappes, M.M., Mechanistic aspects of fullerene coalescence upon ultraviolet laser desorption from thin films, J. Chem. Phys., 1994, 100, 262. [all data]


Notes

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