CF3OOO

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 41000 O2 von Ahsen, Willner, et al., 2003

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
1 OO stretch 1500 w m O2 IR von Ahsen, Willner, et al., 2003
2 CO stretch 1223 vs O2 IR von Ahsen, Willner, et al., 2003
3 CF a-stretch 1211 s O2 IR von Ahsen, Willner, et al., 2003
4 CF a-stretch 1182 s O2 IR von Ahsen, Willner, et al., 2003
5 CF s-stretch 895 w O2 IR von Ahsen, Willner, et al., 2003
6 CF3 umbrella 615 w O2 IR von Ahsen, Willner, et al., 2003
8 CF3 deform. 581 w O2 IR von Ahsen, Willner, et al., 2003
9 CF3 scissors 450 w O2 IR von Ahsen, Willner, et al., 2003
11 OOO bend 239 w O2 IR von Ahsen, Willner, et al., 2003
12 O-O2 stretch 219 w O2 IR von Ahsen, Willner, et al., 2003

Notes

wWeak
mMedium
sStrong
vsVery strong
xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

von Ahsen, Willner, et al., 2003
von Ahsen, S.; Willner, H.; Francisco, J.S., The Trifluoromethyltrioxy Radical, CF3OOO, Angew. Chem. Ind. Ed., 2003, 42, 38, 4690, https://doi.org/10.1002/anie.200351909 . [all data]

Notes

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