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Silylene


Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
B - John E. Bartmess

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Clustering reactions

Iron ion (1+) + Silylene = (Iron ion (1+) bullet Silylene)

By formula: Fe+ + H2Si = (Fe+ bullet H2Si)

Quantity Value Units Method Reference Comment
Deltar280. ± 50.kJ/molICRJacobson and Bakhtiar, 1993gas phase; M

(H3Si- bullet 4294967295Silylene) + Silylene = H3Si-

By formula: (H3Si- bullet 4294967295H2Si) + H2Si = H3Si-

Quantity Value Units Method Reference Comment
Deltar354. ± 5.9kJ/molN/ANimlos and Ellison, 1986gas phase; B
Deltar212. ± 10.kJ/molTherBartmess, Scott, et al., 1979gas phase; value altered from reference due to change in acidity scale; B

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Jacobson and Bakhtiar, 1993
Jacobson, D.B.; Bakhtiar, R., Generation, Characterization and Properties of Iron-Silylene and Iron-Sylene Cationic Complexes in the Gas Phase, J. Am. Chem. Soc., 1993, 115, 23, 10830, https://doi.org/10.1021/ja00076a046 . [all data]

Nimlos and Ellison, 1986
Nimlos, M.R.; Ellison, G.B., Photoelectron spectroscopy of SiH3- and SiD3-, J. Am. Chem. Soc., 1986, 108, 6522. [all data]

Bartmess, Scott, et al., 1979
Bartmess, J.E.; Scott, J.A.; McIver, R.T., Jr., The gas phase acidity scale from methanol to phenol, J. Am. Chem. Soc., 1979, 101, 6047. [all data]


Notes

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