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1-Cyanoethyl radical


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

View reactions leading to C3H4N+ (ion structure unspecified)

Electron affinity determinations

EA (eV) Method Reference Comment
1.766 ± 0.012LPESDuan, Burggraf, et al., 2002B
1.50 ± 0.10LPESNakajima, Taguwa, et al., 1995Vertical Detachment Energy: 1.71±0.10 eV; B

Ionization energy determinations

IE (eV) Method Reference Comment
9.8 ± 0.1EIPottie and Lossing, 1961RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Duan, Burggraf, et al., 2002
Duan, X.F.; Burggraf, L.W.; Weeks, D.E.; Davico, G.E.; Schwartz, R.L.; Lineberger, W.C., Photoelectron spectroscopy of Si2C3- and quantum chemistry of the linear Si2C3 cluster and its isomers, J. Chem. Phys., 2002, 116, 9, 3601-3611, https://doi.org/10.1063/1.1427709 . [all data]

Nakajima, Taguwa, et al., 1995
Nakajima, A.; Taguwa, T.; Nakao, K.; Gomei, M.; Kishi, R.; Iwata, S.; Kaya, K., Photoelectron Spectroscopy of silicon-carbon cluster Anions (SinCm-), J. Chem. Phys., 1995, 103, 6, 2050, https://doi.org/10.1063/1.469731 . [all data]

Pottie and Lossing, 1961
Pottie, R.F.; Lossing, F.P., Free radicals by mass spectrometry. XXV. Ionization potentials of cyanoalkyl radicals, J. Am. Chem. Soc., 1961, 83, 4737. [all data]


Notes

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