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cerium


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
L - Sharon G. Lias

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

View reactions leading to Ce+ (ion structure unspecified)

Quantity Value Units Method Reference Comment
IE (evaluated)5.5387 ± 0.0004eVN/AN/AL

Electron affinity determinations

EA (eV) Method Reference Comment
0.570 ± 0.020LPESFelton, Ray, et al., 2014B
0.628 ± 0.010N/AWalter, Gibson, et al., 2011B
0.650 ± 0.030N/AWalter, Gibson, et al., 2007B
0.66 ± 0.10LPESDavis and Thompson, 2002As reinterpreted by O'Malley and Beck, 2006: true 0->0 threshold too weak to observe; B

Ionization energy determinations

IE (eV) Method Reference Comment
5.5387EVALLide, 1992LL
5.5387 ± 0.0004LSWorden, Solarz, et al., 1978LLK
5.5387 ± 0.0004SMartin, Zalubas, et al., 1978LLK
5.537 ± 0.0004PIPaisner, Solarz, et al., 1977LLK
5.5387 ± 0.0004LSPaisner, Solarz, et al., 1977LLK
5.4 ± 0.1EIAckermann, Rauh, et al., 1976LLK
6.0 ± 0.5EIPiacente, Bardi, et al., 1973LLK
5.6 ± 0.5EIGuido and Gigli, 1973LLK
5.9 ± 0.6EIGingerich, Pupp, et al., 1972LLK
5.7 ± 0.3EICocke and Gingerich, 1972LLK
5.9 ± 0.4EIGingerich, 1971LLK
6.0 ± 0.5EIGingerich and Pupp, 1971LLK
5.47 ± 0.02SMoore, 1970RDSH
5.54 ± 0.06SIHertel, 1968RDSH
5.60 ± 0.05SIIonov and Mittsev, 1961RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Felton, Ray, et al., 2014
Felton, J.; Ray, M.; Jarrold, C.C., Measurement of the electron affinity of atomic Ce, Phys. Rev. A, 2014, 89, 3, 033407, https://doi.org/10.1103/PhysRevA.89.033407 . [all data]

Walter, Gibson, et al., 2011
Walter, C.W.; Gibson, N.D.; Li, Y.G.; Matyas, D.J.; Alton, R.M.; Lou, S.E.; Field, R.L.; Hanstorp, D.; Pan, L.; Beck, D.R., Experimental and theoretical study of bound and quasibound states of Ce-, Phys. Rev. A, 2011, 84, 3, 032514, https://doi.org/10.1103/PhysRevA.84.032514 . [all data]

Walter, Gibson, et al., 2007
Walter, C.W.; Gibson, N.D.; Janczak, C.M.; Starr, K.A.; Snedden, A.P.; Field, R.L.; Andersson, P., Infrared photodetachment of Ce-: Threshold spectroscopy and resonance structure, Phys. Rev. A, 2007, 76, 5, 052702, https://doi.org/10.1103/PhysRevA.76.052702 . [all data]

Davis and Thompson, 2002
Davis, V.T.; Thompson, J.S., Measurement of the electron affinity of cerium, Phys. Rev. Lett., 2002, 88, 7, no.-073, https://doi.org/10.1103/PhysRevLett.88.073003 . [all data]

O'Malley and Beck, 2006
O'Malley, S.M.; Beck, D.R., Calculation of Ce- binding energies by analysis of photodetachment partial cross sections, Phys. Rev. A, 2006, 74, 4, 042509, https://doi.org/10.1103/PhysRevA.74.042509 . [all data]

Lide, 1992
Lide, D.R. (Editor), Ionization potentials of atoms and atomic ions in Handbook of Chem. and Phys., 1992, 10-211. [all data]

Worden, Solarz, et al., 1978
Worden, E.F.; Solarz, R.W.; Paisner, J.A.; Conway, J.G., First ionization potentials of lanthanides by laser spectroscopy, J. Opt. Soc. Am., 1978, 68, 52. [all data]

Martin, Zalubas, et al., 1978
Martin, W.C.; Zalubas, R.; Hagan, L., Atomic energy levels - the rare earth elements, Natl. Stand. Ref. Data Ser. (U.S. Natl. Bur. Stand.), 1978, 60. [all data]

Paisner, Solarz, et al., 1977
Paisner, J.A.; Solarz, R.W.; Worden, E.F.; Conway, J.G., IV. Highly excited states, ionization, and high intensity interactions Identification of Rydberg state in the atomic lanthanides and actinides, Springer Ser. Opt. Sci., 1977, 7, 160. [all data]

Ackermann, Rauh, et al., 1976
Ackermann, R.J.; Rauh, E.G.; Thorn, R.J., The thermodynamics of ionization of gaseous oxides; the first ionization potentials of the lanthanide metals and monoxides, J. Chem. Phys., 1976, 65, 1027. [all data]

Piacente, Bardi, et al., 1973
Piacente, V.; Bardi, G.; Malaspina, L.; Desideri, A., Dissociation energy of CeO2 and Ce2O2 molecules, J. Chem. Phys., 1973, 59, 31. [all data]

Guido and Gigli, 1973
Guido, M.; Gigli, G., Mass spectrometric study of the CeSiC molecules, J. Chem. Phys., 1973, 59, 3437. [all data]

Gingerich, Pupp, et al., 1972
Gingerich, K.A.; Pupp, C.; Campbell, B.E., Mass spectrometric determination of the heats of atomization of the molecules Ce2S, CeS2, Ce2S2, Ce2S3, High Temp. Sci., 1972, 4, 236. [all data]

Cocke and Gingerich, 1972
Cocke, D.L.; Gingerich, K.A., Mass spectrometric determination of the bond dissociation energies of the molecules CePd and CeC2, J. Phys. Chem., 1972, 76, 2332. [all data]

Gingerich, 1971
Gingerich, K.A., Gaseous metal borides. III. The dissociation energy and heat of formation of gold monoboride, J. Chem. Phys., 1971, 54, 2646. [all data]

Gingerich and Pupp, 1971
Gingerich, K.A.; Pupp, C., Mass spectrometric determination of the heats of formation atomization of gaseous AuBO, J. Chem. Phys., 1971, 54, 3713. [all data]

Moore, 1970
Moore, C.E., Ionization potentials and ionization limits derived from the analyses of optical spectra, Natl. Stand. Ref. Data Ser., (U.S. Natl. Bur. Stand.), 1970, 34, 1. [all data]

Hertel, 1968
Hertel, G.R., Surface ionization. III. The first ionization potentials of the lanthanides, J. Chem. Phys., 1968, 48, 2053. [all data]

Ionov and Mittsev, 1961
Ionov, N.I.; Mittsev, M.A., Atomic first ionization potentials determined by the method of surface ionization, Zh. Eksperim. i Teor. Fiz. 1961,40,741 (Engl. Transl.: Soviet Phys. JETP, 1961, 13, 518). [all data]


Notes

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