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2-Chloroadamantane

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltasub61.5 ± 0.8kJ/molMEAbboud, Castaño, et al., 2002AC

Enthalpy of phase transition

DeltaHtrs (kJ/mol) Temperature (K) Initial Phase Final Phase Reference Comment
0.470227.crystaline, IIIcrystaline, IIParoli, Kawai, et al., 1988DH
8.300242.crystaline, IIcrystaline, IParoli, Kawai, et al., 1988DH

Entropy of phase transition

DeltaStrs (J/mol*K) Temperature (K) Initial Phase Final Phase Reference Comment
2.3227.crystaline, IIIcrystaline, IIParoli, Kawai, et al., 1988DH
35.242.crystaline, IIcrystaline, IParoli, Kawai, et al., 1988DH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Abboud, Castaño, et al., 2002
Abboud, José-Luis M.; Castaño, Obis; Dávalos, Juan Z.; Jiménez, Pilar; Gomperts, Roberto; Müller, Paul; Roux, María Victoria, Intrinsic (Gas Phase) Thermodynamic Stability of 2-Adamantyl Cation. Its Bearing on the Solvolysis Rates of 2-Adamantyl Derivatives, J. Org. Chem., 2002, 67, 4, 1057-1060, https://doi.org/10.1021/jo016206f . [all data]

Paroli, Kawai, et al., 1988
Paroli, R.M.; Kawai, N.T.; Butler, I.S.; Gilson, D.F.R., Phase transitions in adamantane derivatives: 2-chloroadamantane, Can. J. Chem., 1988, 66, 1973-1978. [all data]


Notes

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