OF2+

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   E
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 51560 ± 400 gas Cornford, Frost, et al., 1971
Brundle, Robin, et al., 1972

State:   D
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 38650 T gas Cornford, Frost, et al., 1971
Brundle, Robin, et al., 1972

State:   C
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 26880 ± 120 gas Cornford, Frost, et al., 1971
Brundle, Robin, et al., 1972
Wang, Chau, et al., 2001
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 1 OF2 s-stretch 900 ± 50 gas PE Wang, Chau, et al., 2001
2 Bend 480 ± 50 gas PE Wang, Chau, et al., 2001

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 21950 ± 120 gas Cornford, Frost, et al., 1971
Brundle, Robin, et al., 1972
Wang, Chau, et al., 2001
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 2 Bend 440 ± 30 gas PE Wang, Chau, et al., 2001

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 1 OF s-stretch 1020 ± 20 gas PE Cornford, Frost, et al., 1971
Brundle, Robin, et al., 1972
Wang, Chau, et al., 2001

Additional references: Jacox, 1994, page 111; Jacox, 2003, page 148

Notes

TTentative assignment or approximate value
oEnergy separation between the v = 0 levels of the excited and electronic ground states.
xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Cornford, Frost, et al., 1971
Cornford, A.B.; Frost, D.C.; Herring, F.G.; McDowell, C.A., Photoelectron spectra of F2O and Cl2O, J. Chem. Phys., 1971, 55, 2820. [all data]

Brundle, Robin, et al., 1972
Brundle, C.R.; Robin, M.B.; Kuebler, N.A.; Basch, H., Perfluoro effect in photoelectron spectroscopy. I. Nonaromatic molecules, J. Am. Chem. Soc., 1972, 94, 1451. [all data]

Wang, Chau, et al., 2001
Wang, D.-C.; Chau, F.-T.; Mok, D.K.-W.; Lee, E.P.F.; Beeching, L.; Ogden, J.S.; Dyke, J.M., The X [sup 2]B[sub 1], [sup 2]B[sub 2], [sup 2]A[sub 1], and [sup 2]A[sub 2] states of oxygen difluoride cation (F[sub 2]O[sup +]): High-level ab initio calculations and simulation of the ultraviolet photoelectron spectrum of F[sub 2]O, J. Chem. Phys., 2001, 114, 24, 10682, https://doi.org/10.1063/1.1373690 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Notes

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