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(2-FC6H4)CH2


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   A


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 21924 gas A-X 435 524 Bindley, Watts, et al., 1964
Charlton and Thrush, 1986
Lee and Lee, 2001


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

1022 gas LF Charlton and Thrush, 1986
704 gas LF Charlton and Thrush, 1986
501 gas LF Charlton and Thrush, 1986
386 gas LF Charlton and Thrush, 1986

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 7(8a C-CH2 stretch 1570 gas PE EM Kim, Wenthold, et al., 1999
Lee and Lee, 2001
13(14 1285 gas EM Lee and Lee, 2001
14(7a 1264 gas PE EM Kim, Wenthold, et al., 1999
Lee and Lee, 2001
15(13 1208 gas EM Lee and Lee, 2001
(18a) 1119 gas EM Lee and Lee, 2001
(18b) 1033 gas EM Lee and Lee, 2001
20 882 gas LF Charlton and Thrush, 1986
21(1) Ring breathing 757 gas PE EM Kim, Wenthold, et al., 1999
Lee and Lee, 2001
22(6a Ring deform. 575 gas PE EM Kim, Wenthold, et al., 1999
Lee and Lee, 2001
23(6b Ring deform. 516 gas EM Lee and Lee, 2001
24(9b CH2 rock 436 gas PE EM Kim, Wenthold, et al., 1999
Lee and Lee, 2001
25(15 304 gas EM Lee and Lee, 2001
a (5) 969 gas EM Lee and Lee, 2001
(16a) 535 gas EM Lee and Lee, 2001
(16b) 424 gas EM Lee and Lee, 2001
(10a) 266 gas EM Lee and Lee, 2001

Additional references: Jacox, 1998, page 369; Jacox, 2003, page 402

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Bindley, Watts, et al., 1964
Bindley, T.F.; Watts, A.T.; Walker, S., Electronic emission spectra of radicals from fluorotoluenes, Trans. Faraday Soc., 1964, 60, 1, https://doi.org/10.1039/tf9646000001 . [all data]

Charlton and Thrush, 1986
Charlton, T.R.; Thrush, B.A., The study of substituted benzyl radicals by laser-induced fluorescence, Chem. Phys. Lett., 1986, 125, 5-6, 547, https://doi.org/10.1016/0009-2614(86)87096-8 . [all data]

Lee and Lee, 2001
Lee, S.K.; Lee, S.K., Vibronic Spectroscopy of Benzyl-Type Radicals: Jet-Cooled, J. Phys. Chem. A, 2001, 105, 13, 3034, https://doi.org/10.1021/jp003627c . [all data]

Kim, Wenthold, et al., 1999
Kim, J.B.; Wenthold, P.G.; Lineberger, W.C., Ultraviolet Photoelectron Spectroscopy of, J. Phys. Chem. A, 1999, 103, 50, 10833, https://doi.org/10.1021/jp992817o . [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]


Notes

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