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(3-ClC6H4)CH2


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   A


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 21194.8 gas A-X 471 503 Lee and Chae, 2001

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 7 C-CH2 stretch 1520 ± 40 gas PE Kim, Wenthold, et al., 1999
13(3) 1287 gas EM Lee and Chae, 2001
14(13 1237 gas EM Lee and Chae, 2001
18(12 984 gas EM Lee and Chae, 2001
19(5) 959 gas EM Lee and Chae, 2001
21(1) 686 gas PE EM Kim, Wenthold, et al., 1999
Lee and Chae, 2001
22(6a Ring deform. 525 gas PE EM Kim, Wenthold, et al., 1999
Lee and Chae, 2001
23(7b 413 gas EM Lee and Chae, 2001
24(15 394 gas EM Lee and Chae, 2001

Additional references: Jacox, 2003, page 403

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Lee and Chae, 2001
Lee, S.K.; Chae, S.Y., Vibrational Mode Assignments of Jet-Cooled, J. Phys. Chem. A, 2001, 105, 24, 5808, https://doi.org/10.1021/jp0045437 . [all data]

Kim, Wenthold, et al., 1999
Kim, J.B.; Wenthold, P.G.; Lineberger, W.C., Ultraviolet Photoelectron Spectroscopy of, J. Phys. Chem. A, 1999, 103, 50, 10833, https://doi.org/10.1021/jp992817o . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]


Notes

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