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HKrCl


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Tx = 35700 Kr Khriachtchev, Pettersson, et al., 2001

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

Sigma+ 1 HKr stretch 1476 vs Kr IR Pettersson, Lundell, et al., 1995
1 HKr stretch 1589.0 Kr IR Lignell, Khriachtchev, et al., 2002
Lignell, Khriachtchev, et al., 2003
1 HKr stretch 1508.5 Kr IR Lignell, Khriachtchev, et al., 2002
Lignell, Khriachtchev, et al., 2003
Pi 2 Bend 544 w Kr IR Pettersson, Lundell, et al., 1995
2 Bend 541.5 Kr IR Lignell, Khriachtchev, et al., 2002
Lignell, Khriachtchev, et al., 2003
Sigma+ 3 KrCl stretch 253.1 Kr IR Lignell, Lundell, et al., 2003

Additional references: Jacox, 1998, page 158; Jacox, 2003, page 47

Notes

wWeak
vsVery strong
xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Khriachtchev, Pettersson, et al., 2001
Khriachtchev, L.; Pettersson, M.; Lundell, J.; Rasanen, M., Intermediate reactions in solid-state photolysis, J. Chem. Phys., 2001, 114, 18, 7727, https://doi.org/10.1063/1.1370938 . [all data]

Pettersson, Lundell, et al., 1995
Pettersson, M.; Lundell, J.; Rasanen, M., Neutral rare-gas containing charge-transfer molecules in solid matrices. I. HXeCl, HXeBr, HXeI, and HKrCl in Kr and Xe, J. Chem. Phys., 1995, 102, 16, 6423, https://doi.org/10.1063/1.469357 . [all data]

Lignell, Khriachtchev, et al., 2002
Lignell, A.; Khriachtchev, L.; Pettersson, M.; Rasanen, M., Large blueshift of the H--Kr stretching frequency of HKrCl upon complexation with N[sub 2], J. Chem. Phys., 2002, 117, 3, 961, https://doi.org/10.1063/1.1491403 . [all data]

Lignell, Khriachtchev, et al., 2003
Lignell, A.; Khriachtchev, L.; Pettersson, M.; Rasanen, M., Interaction of rare-gas-containing molecules with nitrogen: Matrix-isolation and ab initio study of HArF...N[sub 2], HKrF...N[sub 2], and HKrCl...N[sub 2] complexes, J. Chem. Phys., 2003, 118, 24, 11120, https://doi.org/10.1063/1.1575198 . [all data]

Lignell, Lundell, et al., 2003
Lignell, A.; Lundell, J.; Pettersson, M.; Khriachtchev, L.; Rasanen, M., Kr--Cl stretching vibration of HKrCl: Matrix-isolation and anharmonic ab initio study, Low Temp. Phys., 2003, 29, 9, 844, https://doi.org/10.1063/1.1619355 . [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]


Notes

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