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Chloroketene


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
9.24PEBock, Hirabayashi, et al., 1981Vertical value; LLK
9.35PEBock, Hirabayashi, et al., 1977Vertical value; LLK

Vibrational and/or electronic energy levels

Go To: Top, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 2 CO stretch 2157.19 gas DL Liu, Livingstone, et al., 2000
2 CO stretch 2141.4 vs Xe IR Davidovics, Monnier, et al., 1991
3 HCCl deform. 1293 w Xe IR Davidovics, Monnier, et al., 1991
4 CC stretch 1107 w Xe IR Davidovics, Monnier, et al., 1991
5 CCl stretch 842.2 w Xe IR Davidovics, Monnier, et al., 1991
a 8 HClCC OPLA 747 Xe IR Davidovics, Monnier, et al., 1991

Additional references: Jacox, 1994, page 269; Jacox, 2003, page 273; Gerry, Lewis-Bevan, et al., 1983

Notes

wWeak
vsVery strong

References

Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Bock, Hirabayashi, et al., 1981
Bock, H.; Hirabayashi, T.; Mohmand, S., Thermische erzeugung von alkyl- und halogenketenen, Chem. Ber., 1981, 114, 2595. [all data]

Bock, Hirabayashi, et al., 1977
Bock, H.; Hirabayashi, T.; Mohmand, S.; Solouki, B., Instabile Zwischenprodukte in der Gasphase: Der thermische Zerfall von Carbonsaurechloriden RCOCl, Angew. Chem., 1977, 89, 106. [all data]

Liu, Livingstone, et al., 2000
Liu, Z.; Livingstone, R.J.; Davies, P.B., Pulse Pyrolysis Infrared Laser Jet Spectroscopy of Chloroketene, J. Mol. Spectrosc., 2000, 201, 1, 30, https://doi.org/10.1006/jmsp.2000.8083 . [all data]

Davidovics, Monnier, et al., 1991
Davidovics, G.; Monnier, M.; Allouche, A., FT-IR spectral data and ab initio calculations for haloketenes, Chem. Phys., 1991, 150, 3, 395, https://doi.org/10.1016/0301-0104(91)87112-9 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Gerry, Lewis-Bevan, et al., 1983
Gerry, M.C.L.; Lewis-Bevan, W.; Westwood, N.P.C., The microwave spectrum of an unstable molecule: Chloroketene ClHCCO, J. Chem. Phys., 1983, 79, 10, 4655, https://doi.org/10.1063/1.445606 . [all data]


Notes

Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, References