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C6H5Br+


Vibrational and/or electronic energy levels

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   K


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 63170 ± 100 gas Holland, Edvardsson, et al., 2000


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 (1) 920 ± 10 gas PE Holland, Edvardsson, et al., 2000

State:   J


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Tx = 53300 T gas Holland, Edvardsson, et al., 2000

State:   I


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Tx = 49530 ± 100 gas Holland, Edvardsson, et al., 2000

State:   H


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Tx = 44690 ± 100 gas Holland, Edvardsson, et al., 2000

State:   G


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Tx = 40980 ± 100 gas Holland, Edvardsson, et al., 2000

State:   F


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Tx = 31540 T gas Holland, Edvardsson, et al., 2000

State:   E


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Tx = 29760 ± 100 gas Holland, Edvardsson, et al., 2000

State:   D


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Tx = 24040 ± 100 gas Holland, Edvardsson, et al., 2000

State:   C


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 17730 ± 25 gas Holland, Edvardsson, et al., 2000


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 (12) 605 ± 10 gas PE Holland, Edvardsson, et al., 2000
(6a) 234 ± 10 gas PE Holland, Edvardsson, et al., 2000

State:   B


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 13252 ± 8 gas Holland, Edvardsson, et al., 2000
Kwon, Kim, et al., 2002


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 (8a) 1571 gas TPI Kwon, Kim, et al., 2002
(19a) 1419 gas TPI Kwon, Kim, et al., 2002
(9a) 1180 gas TPI Kwon, Kim, et al., 2002
(7a) 1015 gas TPI Kwon, Kim, et al., 2002
(18a) 982 gas TPI Kwon, Kim, et al., 2002
(1) 959 gas PE TPI Holland, Edvardsson, et al., 2000
Kwon, Kim, et al., 2002
(12) 622 gas PE TPI Holland, Edvardsson, et al., 2000
Kwon, Kim, et al., 2002
b1 (17b) 889 gas TPI Kwon, Kim, et al., 2002
b2 (14) 1333 gas TPI Kwon, Kim, et al., 2002
(3) 1251 gas TPI Kwon, Kim, et al., 2002
(9b) 1130 gas TPI Kwon, Kim, et al., 2002
(6b) 542 gas TPI Kwon, Kim, et al., 2002

State:   A


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 5420 ± 25 gas Holland, Edvardsson, et al., 2000


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 (12) 775 ± 10 gas PE Holland, Edvardsson, et al., 2000
(6a) 258 ± 10 gas PE Holland, Edvardsson, et al., 2000

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 3083 T gas TPI Kwon, Kim, et al., 2002
(8a) 1577 gas TPI PE Walter, Scherm, et al., 1991
Kwon, Kim, et al., 2002
(19a) 1466 gas TPI Kwon, Kim, et al., 2002
(9a) 1193 gas TPI Kwon, Kim, et al., 2002
(7a) 1073 gas TPI PE Walter, Scherm, et al., 1991
Kwon, Kim, et al., 2002
(18a) 1008 gas TPI PE Walter, Scherm, et al., 1991
Holland, Edvardsson, et al., 2000
Kwon, Kim, et al., 2002
(12) 678 gas TPI Kwon, Kim, et al., 2002
(6a) 331 gas TPI PE Walter, Scherm, et al., 1991
Holland, Edvardsson, et al., 2000
Kwon, Kim, et al., 2002
a2 (16a) 396 gas TPI Kwon, Kim, et al., 2002
b1 (10b) 791 gas TPI Kwon, Kim, et al., 2002
(11) 126 gas TPI Kwon, Kim, et al., 2002
b2 (8b) 1523 gas TPI Kwon, Kim, et al., 2002
(14) 1307 gas TPI Kwon, Kim, et al., 2002
(6b) 593 gas TPI PE Walter, Scherm, et al., 1991
Kwon, Kim, et al., 2002
(18b) 257 gas TPI Kwon, Kim, et al., 2002

Additional references: Jacox, 2003, page 399

Notes

TTentative assignment or approximate value
oEnergy separation between the v = 0 levels of the excited and electronic ground states.
xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Holland, Edvardsson, et al., 2000
Holland, D.M.P.; Edvardsson, D.; Karlsson, L.; Maripuu, R.; Siegbahn, K.; Potts, A.W.; von Niessen, W., An experimental and theoretical study of the valence shell photoelectron spectrum of bromobenzene, Chem. Phys., 2000, 252, 1-2, 257, https://doi.org/10.1016/S0301-0104(99)00346-8 . [all data]

Kwon, Kim, et al., 2002
Kwon, C.H.; Kim, H.L.; Kim, M.S., Vibrational spectra of halobenzene cations in the ground and B [sup 2]B[sub 2] electronic states obtained by one-photon mass-analyzed threshold ionization spectrometry, J. Chem. Phys., 2002, 116, 23, 10361, https://doi.org/10.1063/1.1478695 . [all data]

Walter, Scherm, et al., 1991
Walter, K.; Scherm, K.; Boesl, U., Spectroscopy of the ionic ground state of monohalogenated benzenes, J. Phys. Chem., 1991, 95, 3, 1188, https://doi.org/10.1021/j100156a029 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]


Notes

Go To: Top, Vibrational and/or electronic energy levels, References