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C2H5S+


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   B


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Txx = 34940 ± 240 gas Ge, Wang, et al., 2000

State:   A


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Txx = 26380 ± 240 gas Ge, Wang, et al., 2000

State:   b


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Txx = 11460 ± 240 gas Ge, Wang, et al., 2000

State:   a


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Txx = 9920 ± 240 gas Ge, Wang, et al., 2000

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

CS stretch 670 ± 30 gas PE Cheung, Hsu, et al., 1998
Ge, Wang, et al., 2000

Additional references: Jacox, 2003, page 352

Notes

xxEnergy separation between the band maxima of both the excited state and the ground state of a molecular cation, derived from a photoelectron spectrum.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ge, Wang, et al., 2000
Ge, M.; Wang, J.; Zhu, X.; Sun, Z.; Wang, D., Experimental and theoretical studies on different ionic states of ethylthio CH[sub 3]CH[sub 2]S radical, J. Chem. Phys., 2000, 113, 5, 1866, https://doi.org/10.1063/1.481990 . [all data]

Cheung, Hsu, et al., 1998
Cheung, Y.-S.; Hsu, C.-W.; Ng, C.Y., Non-resonant two photon pulsed field ionization photoelectron study of CH3CH2S formed in the photodissociation of CH3CH2SH, J. Electron Spectrosc. Relat. Phenom., 1998, 97, 1-2, 115, https://doi.org/10.1016/S0368-2048(98)00262-X . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]


Notes

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