SO4 radical


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity determinations

EA (eV) Method Reference Comment
5.10 ± 0.10LPESWang, Nicholas, et al., 2000 

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

S=O stretch 1443 s Ar IR Kugel and Taube, 1975
Chaabouni, Schriver-Mazzuoli, et al., 2000
S=O stretch 1273 s Ar IR Kugel and Taube, 1975
Chaabouni, Schriver-Mazzuoli, et al., 2000
O-O stretch 925 w m Ar IR Kugel and Taube, 1975
777 w m Ar IR Kugel and Taube, 1975
611 m Ar IR Kugel and Taube, 1975
498 s Ar IR Kugel and Taube, 1975
490 s Ar IR Kugel and Taube, 1975

Additional references: Jacox, 1994, page 289; Jacox, 2003, page 302

Notes

wWeak
mMedium
sStrong

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Wang, Nicholas, et al., 2000
Wang, X.B.; Nicholas, J.B.; Wang, L.S., Photoelectron spectroscopy and theoretical calculations of SO4- and HSO4-: Confirmation of high electron affinities of SO4 and HSO4, J. Phys. Chem. A, 2000, 104, 3, 504-508, https://doi.org/10.1021/jp992726r . [all data]

Kugel and Taube, 1975
Kugel, R.; Taube, H., Infrared spectrum and structure of matrix-isolated sulfur tetroxide, J. Phys. Chem., 1975, 79, 20, 2130, https://doi.org/10.1021/j100587a014 . [all data]

Chaabouni, Schriver-Mazzuoli, et al., 2000
Chaabouni, H.; Schriver-Mazzuoli, L.; Schriver, A., Conversion of SO, J. Phys. Chem. A, 2000, 104, 16, 3498, https://doi.org/10.1021/jp993164e . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]


Notes

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