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H3+


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1' 1 Ring breathing 3178.18 gas IR LD Majewski, Marshall, et al., 1987
Lembo, Petit, et al., 1989
Ketterle, Messmer, et al., 1989
Xu, Rosslein, et al., 1992
Majewski, McKellar, et al., 1994
e' 2 Deformation 2521.42 gas LD Oka, 1980
Watson, Foster, et al., 1984
Nakanaga, Ito, et al., 1990
Majewski, McKellar, et al., 1994
McKellar and Watson, 1998
2 Deformation 2521.42 gas EM Civis, Kubat, et al., 2006
2 Deformation 2109.7 T H2 IR Chan, Okumura, et al., 2000

Additional references: Jacox, 1994, page 11; Jacox, 1998, page 123; Jacox, 2003, page 9; Shy, Farley, et al., 1980; Amano and Watson, 1984; Lubic and Amano, 1984; Amano, 1985; Foster, McKellar, et al., 1986; Foster, McKellar, et al., 1986, 2; Watson, Foster, et al., 1987; Kozin, Polyansky, et al., 1988; Polyansky and McKellar, 1990; Bawendi, Rehfuss, et al., 1990; Xu, Gabrys, et al., 1990; Lee, Ventrudo, et al., 1991; Ventrudo, Cassidy, et al., 1994; Amano, Chan, et al., 1994; Amano and Hirao, 2005

Notes

TTentative assignment or approximate value

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Majewski, Marshall, et al., 1987
Majewski, W.A.; Marshall, M.D.; McKellar, A.R.W.; Johns, J.W.C.; Watson, J.K.G., Higher rotational lines in the «nu»2 fundamental of the H3+ molecular ion, J. Mol. Spectrosc., 1987, 122, 2, 341, https://doi.org/10.1016/0022-2852(87)90009-9 . [all data]

Lembo, Petit, et al., 1989
Lembo, L.J.; Petit, A.; Helm, H., Vibrational autoionization in H_{3} and measurements of the symmetric-stretch frequency of the metastable 2p A_{2}^{''} state, Phys. Rev. A, 1989, 39, 7, 3721, https://doi.org/10.1103/PhysRevA.39.3721 . [all data]

Ketterle, Messmer, et al., 1989
Ketterle, W.; Messmer, H.-P.; Walther, H., The «nu», Europhys. Lett., 1989, 8, 4, 333, https://doi.org/10.1209/0295-5075/8/4/006 . [all data]

Xu, Rosslein, et al., 1992
Xu, L.-W.; Rosslein, M.; Gabrys, C.M.; Oka, T., Observation of infrared forbidden transitions of H3+, J. Mol. Spectrosc., 1992, 153, 1-2, 726, https://doi.org/10.1016/0022-2852(92)90507-K . [all data]

Majewski, McKellar, et al., 1994
Majewski, W.A.; McKellar, A.R.W.; Sadovskii, D.; Watson, J.K.G., New observations and analysis of the infrared vibration--rotation spectrum of H, Can. J. Phys., 1994, 72, 11-12, 1016, https://doi.org/10.1139/p94-133 . [all data]

Oka, 1980
Oka, T., Observation of the Infrared Spectrum of H_{3}^{+}, Phys. Rev. Lett., 1980, 45, 7, 531, https://doi.org/10.1103/PhysRevLett.45.531 . [all data]

Watson, Foster, et al., 1984
Watson, J.K.G.; Foster, S.C.; McKellar, A.R.W.; Bernath, P.; Amano, T.; Pan, F.S.; Crofton, M.W.; Altman, R.S.; Oka, T., The infrared spectrum of the «nu», Can. J. Phys., 1984, 62, 12, 1875, https://doi.org/10.1139/p84-231 . [all data]

Nakanaga, Ito, et al., 1990
Nakanaga, T.; Ito, F.; Sugawara, K.; Takeo, H.; Matsumura, C., Observation of infrared absorption spectra of molecular ions, H3+ and HN2+, by FTIR spectroscopy, Chem. Phys. Lett., 1990, 169, 3, 269, https://doi.org/10.1016/0009-2614(90)85199-M . [all data]

McKellar and Watson, 1998
McKellar, A.R.W.; Watson, J.K.G., The Infrared Spectrum of H+3Revealed, J. Mol. Spectrosc., 1998, 191, 1, 215, https://doi.org/10.1006/jmsp.1998.7613 . [all data]

Civis, Kubat, et al., 2006
Civis, S.; Kubat, P.; Nishida, S.; Kawaguchi, K., Time-resolved Fourier transform infrared emission spectroscopy of molecular ion, Chem. Phys Lett., 2006, 418, 4-6, 448, https://doi.org/10.1016/j.cplett.2005.10.136 . [all data]

Chan, Okumura, et al., 2000
Chan, M.-C.; Okumura, M.; Oka, T., Infrared Spectrum of, J. Phys. Chem. A, 2000, 104, 16, 3775, https://doi.org/10.1021/jp993890h . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Shy, Farley, et al., 1980
Shy, J.-T.; Farley, J.W.; Lamb, W.E., Jr.; Wing, W.H., Observation of the Infrared Spectrum of the Triatomic Deuterium Molecular Ion D_{3}^{+}, Phys. Rev. Lett., 1980, 45, 7, 535, https://doi.org/10.1103/PhysRevLett.45.535 . [all data]

Amano and Watson, 1984
Amano, T.; Watson, J.K.G., Observation of the «nu»1 fundamental band of H2D+, J. Chem. Phys., 1984, 81, 7, 2869, https://doi.org/10.1063/1.448059 . [all data]

Lubic and Amano, 1984
Lubic, K.G.; Amano, T., Observation of the «nu», Can. J. Phys., 1984, 62, 12, 1886, https://doi.org/10.1139/p84-232 . [all data]

Amano, 1985
Amano, T., Difference-frequency laser spectroscopy of molecular ions with a hollow-cathode cell: extended analysis of the «nu»_1 band of H_2D^+, J. Opt. Soc. Am. B, 1985, 2, 5, 790, https://doi.org/10.1364/JOSAB.2.000790 . [all data]

Foster, McKellar, et al., 1986
Foster, S.C.; McKellar, A.R.W.; Peterkin, I.R.; Watson, J.K.G.; Pan, F.S.; Crofton, M.W.; Altman, R.S.; Oka, T., Observation and analysis of the «nu»2 and «nu»3 fundamental bands of the H2D+ ion, J. Chem. Phys., 1986, 84, 1, 91, https://doi.org/10.1063/1.450137 . [all data]

Foster, McKellar, et al., 1986, 2
Foster, S.C.; McKellar, A.R.W.; Watson, J.K.G., Observation and analysis of the «nu»2 and «nu»3 fundamental bands of the D2H+ ion, J. Chem. Phys., 1986, 85, 2, 664, https://doi.org/10.1063/1.451841 . [all data]

Watson, Foster, et al., 1987
Watson, J.K.G.; Foster, S.C.; McKellar, A.R.W., The infrared spectrum of the «nu», Can. J. Phys., 1987, 65, 1, 38, https://doi.org/10.1139/p87-008 . [all data]

Kozin, Polyansky, et al., 1988
Kozin, I.N.; Polyansky, O.L.; Zobov, N.F., Improved analysis of the experimental data on the H2D+ and D2H+ absorption spectra, J. Mol. Spectrosc., 1988, 128, 1, 126, https://doi.org/10.1016/0022-2852(88)90212-3 . [all data]

Polyansky and McKellar, 1990
Polyansky, O.L.; McKellar, A.R.W., Improved analysis of the infrared spectrum of D2H+, J. Chem. Phys., 1990, 92, 7, 4039, https://doi.org/10.1063/1.457817 . [all data]

Bawendi, Rehfuss, et al., 1990
Bawendi, M.G.; Rehfuss, B.D.; Oka, T., Laboratory observation of hot bands of H+3, J. Chem. Phys., 1990, 93, 9, 6200, https://doi.org/10.1063/1.458989 . [all data]

Xu, Gabrys, et al., 1990
Xu, L.-W.; Gabrys, C.; Oka, T., Observation of the 2«nu»2(l=2)<--0 overtone band of H+3, J. Chem. Phys., 1990, 93, 9, 6210, https://doi.org/10.1063/1.458990 . [all data]

Lee, Ventrudo, et al., 1991
Lee, S.S.; Ventrudo, B.F.; Cassidy, D.T.; Oka, T.; Miller, S.; Tennyson, J., Observation of the 3«nu»2 <-- 0 overtone band of H3+, J. Mol. Spectrosc., 1991, 145, 1, 222, https://doi.org/10.1016/0022-2852(91)90365-H . [all data]

Ventrudo, Cassidy, et al., 1994
Ventrudo, B.F.; Cassidy, D.T.; Guo, Z.Y.; Joo, S.; Lee, S.S.; Oka, T., Near infrared 3«nu»2 overtone band of H+3, J. Chem. Phys., 1994, 100, 9, 6162, https://doi.org/10.1063/1.467088 . [all data]

Amano, Chan, et al., 1994
Amano, T.; Chan, M.-C.; Civis, S.; McKellar, A.R.W.; Majewski, W.A.; Sadovskii, D.; Watson, J.K.G., The infrared vibration--rotation spectrum of the molecular ion: extension to higher vibrational and rotational quantum numbers, Can. J. Phys., 1994, 72, 11-12, 1007, https://doi.org/10.1139/p94-132 . [all data]

Amano and Hirao, 2005
Amano, T.; Hirao, T., Accurate rest frequencies of submillimeter-wave lines of H2D+ and D2H+, J. Mol. Spectrosc., 2005, 233, 1, 7, https://doi.org/10.1016/j.jms.2005.05.008 . [all data]


Notes

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