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1,1-Dimethyl-1-silacyclo-3-pentene


Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Reference
7.77166.8Bykova, Lebedev, et al., 2000

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
9.0PEKhvostenko, Zykov, et al., 1981Vertical value; LLK
9.1 ± 0.03PEGuimon, Pfister-Guillouzo, et al., 1978Vertical value; LLK
9.0PESchweig, Weidner, et al., 1972Vertical value; LLK

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Chemical Concepts
NIST MS number 151341

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References

Go To: Top, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), NIST Free Links, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Bykova, Lebedev, et al., 2000
Bykova, T.A.; Lebedev, B.V.; Ushakov, N.V.; Finkel'shtein, E.Sh., Thermodynamics of the metathesis polymerization of 1,1-dimethyl-1-silacyclopent-3-ene in bulk and the thermodynamic properties of the resulting polymer in the 0-340 K range, Polymer Sci. Ser. A, 2000, 42, 8, 863. [all data]

Khvostenko, Zykov, et al., 1981
Khvostenko, V.I.; Zykov, B.G.; Yuriev, V.P.; Mironov, V.F.; Kovel'zon, G.I.; Panasenko, A.A.; Sheludyakov, V.D.; Gailyunas, I.A., Study of d(«pi»)-p(«pi») interaction in vinyl- and alkylsilicon-containing compounds by photoelectron spectroscopy, J. Organomet. Chem., 1981, 218, 155. [all data]

Guimon, Pfister-Guillouzo, et al., 1978
Guimon, C.; Pfister-Guillouzo, G.; Manuel, G.; Mazerolles, P., Structure electronique de silacyclopentenes-2 et-3, J. Organomet. Chem., 1978, 149, 149. [all data]

Schweig, Weidner, et al., 1972
Schweig, A.; Weidner, U.; Manuel, G., Photoelektronen-Spektroskopie und transannulare Wechselwirkungen - Zur Frage transannularer d-«pi»-Wechselwirkung in 1-Sila- und 1-Germa-3- cyclopentenen, Angew. Chem., 1972, 84, 899. [all data]


Notes

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