BrOCl


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   B


 Energy 
 (cm-1
 Med.   Transition   λmin 
 (nm) 
 λmax 
 (nm) 
 References

Tx = 36760 gas B-X Burkholder, Knight, et al., 2000

State:   A


 Energy 
 (cm-1
 Med.   Transition   λmin 
 (nm) 
 λmax 
 (nm) 
 References

Tx = 31250 gas A-X Burkholder, Knight, et al., 2000

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 1 ClO stretch 675.9 Ar IR Bahou, Schriver-Mazzuoli, et al., 1997
3 BrO stretch 559.5 Ar IR Bahou, Schriver-Mazzuoli, et al., 1997

Additional references: Jacox, 1998, page 207; Jacox, 2003, page 151

Notes

xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Burkholder, Knight, et al., 2000
Burkholder, J.B.; Knight, G.; Orlando, J.J., UV absorption spectrum of BrOCl, J. Photochem. Photobiol. A, 2000, 134, 1-2, 133, https://doi.org/10.1016/S1010-6030(00)00261-6 . [all data]

Bahou, Schriver-Mazzuoli, et al., 1997
Bahou, M.; Schriver-Mazzuoli, L.; Schriver, A.; Chaquin, P., Structure and selective visible photodissociation of the O3:Br2 and O3:BrCl complexes: An infrared matrix isolation and ab initio study, Chem. Phys., 1997, 216, 1-2, 105, https://doi.org/10.1016/S0301-0104(96)00375-8 . [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]


Notes

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