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AlCN


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   A


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 28755.3 ± 0.3 gas A-X 325 405 Fukushima, 1998
Gerasimov, Yang, et al., 1999

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

Sigma+ 1 CN stretch 1974.5 ± 1.5 gas LF Fukushima, 1998
Gerasimov, Yang, et al., 1999
CN stretch 2143.7 Ar IR Lanzisera and Andrews, 1997
Pi 2 Bend 131.9 ± 1.3 gas LF Fukushima, 1998
Gerasimov, Yang, et al., 1999
Sigma+ 3 AlC stretch 523.5 ± 0.7 gas LF Fukushima, 1998
Gerasimov, Yang, et al., 1999

Additional references: Jacox, 2003, page 79; Walker and Gerry, 1999

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Fukushima, 1998
Fukushima, M., Laser induced fluorescence spectroscopy of AlNC/AlCN in supersonic free expansions, Chem. Phys. Lett., 1998, 283, 5-6, 337, https://doi.org/10.1016/S0009-2614(97)01408-5 . [all data]

Gerasimov, Yang, et al., 1999
Gerasimov, I.; Yang, X.; Dagdigian, P.J., Laser fluorescence excitation spectra of the AlNC and AlCN isomers, J. Chem. Phys., 1999, 110, 1, 220, https://doi.org/10.1063/1.478097 . [all data]

Lanzisera and Andrews, 1997
Lanzisera, D.V.; Andrews, L., Reactions of Laser-Ablated Al, Ga, In, and Tl Atoms with Hydrogen Cyanide in Excess Argon. Matrix Infrared Spectra and Density Functional Theory Calculations on New Cyanide and Isocyanide Products, J. Phys. Chem. A, 1997, 101, 50, 9660, https://doi.org/10.1021/jp972333x . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Walker and Gerry, 1999
Walker, K.A.; Gerry, M.C.L., Laboratory microwave spectroscopy of aluminium cyanide, Chem. Phys. Lett., 1999, 301, 1-2, 200, https://doi.org/10.1016/S0009-2614(99)00013-5 . [all data]


Notes

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