HOSi+


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

Σ+ 1 OH stretch 3662.36 gas LD Warner, Fox, et al., 1989
1 OH stretch 3654 ± 3 H gas PF Olkhov and Dopfer, 1999
1 OH stretch 3626.7 ± 0.6 gas PF Olkhov and Dopfer, 1999
1 OH stretch 3444.94 A gas PF Olkhov, Nizkorodov, et al., 1998
1 OH stretch 3145.3 ± 0.5 gas PF Olkhov and Dopfer, 1999
3 SiO stretch 1127.01 gas DL Moazzen-Ahmadi, McKellar, et al., 1989

Additional references: Jacox, 1994, page 39

Notes

H(1/2)(2ν)
A0~1 cm-1 uncertainty

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Warner, Fox, et al., 1989
Warner, H.E.; Fox, A.; Amano, T.; Bohme, D.K., The observation of the ν1 fundamental bands of HOSi+ and DOSi+, J. Chem. Phys., 1989, 91, 9, 5310, https://doi.org/10.1063/1.457578 . [all data]

Olkhov and Dopfer, 1999
Olkhov, R.V.; Dopfer, O., Spectroscopic and ab initio studies of ionic hydrogen bonds: the O--H stretch vibration of SiOH+--X dimers (X=He, Ne, Ar, N2), Chem. Phys. Lett., 1999, 314, 3-4, 215, https://doi.org/10.1016/S0009-2614(99)01165-3 . [all data]

Olkhov, Nizkorodov, et al., 1998
Olkhov, R.V.; Nizkorodov, S.A.; Dopfer, O., Infrared photodissociation spectra of isomeric SiOH+--Arn (n=1--10) complexes, Chem. Phys., 1998, 239, 1-3, 393, https://doi.org/10.1016/S0301-0104(98)00253-5 . [all data]

Moazzen-Ahmadi, McKellar, et al., 1989
Moazzen-Ahmadi, N.; McKellar, A.R.W.; Warner, H.E.; Amano, T., Observation of the ν3 fundamental bands of HOSi+ and DOSi+, J. Chem. Phys., 1989, 91, 9, 5313, https://doi.org/10.1063/1.457633 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]


Notes

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