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BO anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

BO- + Hydrogen cation = Boron hydride oxide

By formula: BO- + H+ = HBO

Quantity Value Units Method Reference Comment
Deltar360.5 ± 6.5kcal/molD-EAWenthold, Kim, et al., 1997gas phase

Gas phase ion energetics data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
2.510 ± 0.015LPESZhai, Wang, et al., 2007 
2.5080 ± 0.0080LPESWenthold, Kim, et al., 1997 
>2.48199TDEqJensen, 1970 
2.832 ± 0.091TDEqSrivastava, Uy, et al., 1971EA(BO) < EA(Cl) by 18 kcal, new «DELTA»Hf(BO) and EA(Cl) used. G2: EA=2.58 eV, Jursic, 1999

Protonation reactions

BO- + Hydrogen cation = Boron hydride oxide

By formula: BO- + H+ = HBO

Quantity Value Units Method Reference Comment
Deltar360.5 ± 6.5kcal/molD-EAWenthold, Kim, et al., 1997gas phase

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Wenthold, Kim, et al., 1997
Wenthold, P.G.; Kim, J.B.; Jonas, K.-L.; Lineberger, W.C., An Experimental and Computational Study of the Electron Affinity of Boron Oxide, J. Phys. Chem. A, 1997, 101, 24, 4472, https://doi.org/10.1021/jp970645u . [all data]

Zhai, Wang, et al., 2007
Zhai, H.J.; Wang, L.M.; Li, S.D.; Wang, L.S., Vibrationally resolved photoelectron spectroscopy of BO- and BO2-: A joint experimental and theoretical study, J. Phys. Chem. A, 2007, 111, 6, 1030-1035, https://doi.org/10.1021/jp0666939 . [all data]

Jensen, 1970
Jensen, D.E., Electron Attachment and Compound Formation in Flames. II. Mass Spectrometry of Boron-Containing Flames, J. Chem. Phys., 1970, 52, 6, 3305, https://doi.org/10.1063/1.1673481 . [all data]

Srivastava, Uy, et al., 1971
Srivastava, R.D.; Uy, O.M.; Farber, M., Effusion mass spectrometric study of thermodynamic properties of BO- and BO2-, J. Chem. Soc. Faraday Trans., 1971, 67, 2941. [all data]

Jursic, 1999
Jursic, B.S., Gaussian, complete basis set, and density functional theory methods evaluation of the electron affinity for BO, B, and O, Theochem-J. Mol. Struct., 1999, 467, 1, 1-6, https://doi.org/10.1016/S0166-1280(98)00378-9 . [all data]


Notes

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References