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Osmium, dodecacarbonyltri-, triangulo


Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltasub105. ± 20.kJ/molN/APilcher and Skinner, 1983See also Connor, Skinner, et al., 1973.; AC
Deltasub105. ± 20.kJ/molTD-HFCConnor, Skinner, et al., 1973MS

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Reference Comment
101.7520.Gaidym, Baev, et al., 1974Based on data from 497. - 543. K.; AC

Enthalpy of sublimation

DeltasubH (kJ/mol) Temperature (K) Reference Comment
134.4 ± 0.4349. - 396.Chandra, Garner, et al., 1999AC
108.4483.Gaidym, Baev, et al., 1974, 2Based on data from 423. - 543. K.; AC

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A., Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2 . [all data]

Connor, Skinner, et al., 1973
Connor, J.A.; Skinner, H.A.; Virmani, Y., High temperature microcalorimetric studies of the thermal decomposition and iodination of polynuclear carbonyls of Fe, Co, Ru, Rh, Re, Os and Ir, Faraday Symp. Chem. Soc., 1973, 8, 18, https://doi.org/10.1039/fs9730800018 . [all data]

Gaidym, Baev, et al., 1974
Gaidym, I.L.; Baev, A.K.; Syrkin, V.G.; Uel'skii, A.A.; Medvedeva, A.E., Russ. J. Phys. Chem., 1974, 48, 1111. [all data]

Chandra, Garner, et al., 1999
Chandra, D.; Garner, M.L.; Lau, K.H., Vapor pressures of osmium, rhodium, and ruthenium carbonyls, JPE, 1999, 20, 6, 565-572, https://doi.org/10.1361/105497199770340554 . [all data]

Gaidym, Baev, et al., 1974, 2
Gaidym, I.L.; Baev, A.K.; Syrkin, V.G.; Uel'skii, A.A.; Medvedeva, A.V., Zh. Fiz. Khim., 1974, 48, 1871. [all data]


Notes

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