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P4


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 1 600.5 gas Ra Bosworth, Clark, et al., 1970
Edwards, 1993
Persson, Taylor, et al., 1997
1 613.6 ± 0.3 Ar Ra Kornath, Kaufmann, et al., 2002
1 611.7 ± 0.3 Kr Ra Kornath, Kaufmann, et al., 2002
1 617.1 ± 0.3 Xe Ra Kornath, Kaufmann, et al., 2002
1 611.4 ± 0.3 Xe Ra Kornath, Kaufmann, et al., 2002
1 613.1 ± 0.3 N2 Ra Kornath, Kaufmann, et al., 2002
e 2 360.8 gas Ra Bosworth, Clark, et al., 1970
Brassington, Edwards, et al., 1981
Edwards, 1993
Persson, Taylor, et al., 1997
2 371.8 ± 0.3 Ar Ra Kornath, Kaufmann, et al., 2002
2 370.1 ± 0.3 Kr Ra Kornath, Kaufmann, et al., 2002
2 371.5 ± 0.3 Xe Ra Kornath, Kaufmann, et al., 2002
2 369 Xe Ra Kornath, Kaufmann, et al., 2002
2 372.0 ± 0.3 N2 Ra Kornath, Kaufmann, et al., 2002
f2 3 466.29 gas IR Ra Gutowsky and Hoffman, 1950
Bosworth, Clark, et al., 1970
Edwards, 1993
Persson, Taylor, et al., 1997
Boudon, Mkadmi, et al., 1999
3 465.8 Ar IR Bauschlicher, Zhou, et al., 2000
Kornath, Kaufmann, et al., 2002
3 465.6 ± 0.3 Kr IR Kornath, Kaufmann, et al., 2002
3 469.6 ± 0.3 Xe IR Kornath, Kaufmann, et al., 2002
3 465.6 ± 0.3 Xe IR Kornath, Kaufmann, et al., 2002
3 467.3 N2 IR Kornath, Kaufmann, et al., 2002

Additional references: Jacox, 2003, page 230


References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Bosworth, Clark, et al., 1970
Bosworth, Y.M.; Clark, R.J.H.; Rippon, D.M., The vapor phase Raman spectra, Raman band contour analyses, and Coriolis constants of the spherical top molecules MF6 (M«58875»S, Se, Te, Mo, W, or U), M(CH3)4 (M«58875»C, Si, Ge, Sn, or Pb), P4, As4 and OsO4, H. Mol. Sectrosc., 1970, 46, 2, 240, https://doi.org/10.1016/0022-2852(73)90040-4 . [all data]

Edwards, 1993
Edwards, H.G.M., Vibrational raman spectrum and force constants of phosphorus, P4, J. Mol. Struct., 1993, 295, 95, https://doi.org/10.1016/0022-2860(93)85009-J . [all data]

Persson, Taylor, et al., 1997
Persson, B.; Taylor, R.; Lee, T., Ab initio geometry, quartic force field, and vibrational frequencies for P[sub 4], J. Chem. Phys., 1997, 107, 13, 5051, https://doi.org/10.1063/1.474868 . [all data]

Kornath, Kaufmann, et al., 2002
Kornath, A.; Kaufmann, A.; Torheyden, M., Raman spectroscopic studies on matrix-isolated phosphorus molecules P[sub 4] and P[sub 2], J. Chem. Phys., 2002, 116, 8, 3323, https://doi.org/10.1063/1.1436112 . [all data]

Brassington, Edwards, et al., 1981
Brassington, N.J.; Edwards, H.G.M.; Long, D.A., The vibration-rotation Raman spectrum of P4, J. Raman Spectrosc., 1981, 11, 5, 346, https://doi.org/10.1002/jrs.1250110511 . [all data]

Gutowsky and Hoffman, 1950
Gutowsky, H.; Hoffman, C., The Infrared Spectrum of P4, J. Am. Chem. Soc., 1950, 72, 12, 5751, https://doi.org/10.1021/ja01168a505 . [all data]

Boudon, Mkadmi, et al., 1999
Boudon, V.; Mkadmi, E.B.; Burger, H.; Pierre, G., High-resolution Fourier transform infrared spectroscopy and analysis of the «nu»3 fundamental band of P4, Chem. Phys. Lett., 1999, 305, 1-2, 21, https://doi.org/10.1016/S0009-2614(99)00348-6 . [all data]

Bauschlicher, Zhou, et al., 2000
Bauschlicher, C.W., Jr.; Zhou, M.; Andrews, L., A Study of the Products of the Reaction of Phosphorus and Dioxygen, J. Phys. Chem. A, 2000, 104, 16, 3566, https://doi.org/10.1021/jp993623b . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]


Notes

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