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Amidogen, methylene-


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
B - John E. Bartmess

View reactions leading to CH2N+ (ion structure unspecified)

Electron affinity determinations

EA (eV) Method Reference Comment
0.5110 ± 0.0080LPESCowles, Travers, et al., 1991B
0.510 ± 0.069IMRBKass and DePuy, 1985EA: between O2 and cyclooctatetraene; B

Ionization energy determinations

IE (eV) Method Reference Comment
9.4 ± 0.1PINesbitt, Marston, et al., 1991LL

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Cowles, Travers, et al., 1991
Cowles, D.C.; Travers, M.J.; Frueh, J.L.; Ellison, G.B., Photoelectron Spectroscopy of CH2N-, J. Chem. Phys., 1991, 94, 5, 3517, https://doi.org/10.1063/1.459773 . [all data]

Kass and DePuy, 1985
Kass, S.R.; DePuy, C.H., Gas phase ion chemistry of azides. The generation of CH=N- and CH2=NCH2-, J. Org. Chem., 1985, 50, 2874. [all data]

Nesbitt, Marston, et al., 1991
Nesbitt, F.L.; Marston, G.; Stief, L.J.; Wickramaaratchi, M.A.; Tao, W.; Klemm, R.B., Measurement of the photoionization spectra and ionization thresholds of the H2CN and D2CN radicals, J. Phys. Chem., 1991, 95, 7613. [all data]


Notes

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