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CH2CFO


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   B


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 29867.4 gas B-X 260 335 Furubayashi, Bridier, et al., 1997
Wright and Dagdigian, 1997
Yamaguchi, Furubayashi, et al., 1998
Inomata, Furubayashi, et al., 1999
Hoops, Gascooke, et al., 2004


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 3 CO stretch 1790 gas LF PF Furubayashi, Bridier, et al., 1997
Inomata, Furubayashi, et al., 1999
Hoops, Gascooke, et al., 2004
4 CH2 scissors 1409 gas LF PF Inomata, Furubayashi, et al., 1999
Hoops, Gascooke, et al., 2004
5 CF stretch 1253 gas LF PF Furubayashi, Bridier, et al., 1997
Inomata, Furubayashi, et al., 1999
Hoops, Gascooke, et al., 2004
6 CH2 rock 911 gas LF PF Furubayashi, Bridier, et al., 1997
Inomata, Furubayashi, et al., 1999
Hoops, Gascooke, et al., 2004
7 CC stretch 874 gas LF PF Furubayashi, Bridier, et al., 1997
Inomata, Furubayashi, et al., 1999
Hoops, Gascooke, et al., 2004
8 FCO bend 537 gas LF PF Furubayashi, Bridier, et al., 1997
Inomata, Furubayashi, et al., 1999
Hoops, Gascooke, et al., 2004
9 CCO bend 421 gas LF PF Furubayashi, Bridier, et al., 1997
Inomata, Furubayashi, et al., 1999
Hoops, Gascooke, et al., 2004

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 3 CO stretch 1724 gas LF Furubayashi, Bridier, et al., 1997
4 CH2 scissors 1475 gas LF Inomata, Furubayashi, et al., 1999
5 CF stretch 1211 gas LF Furubayashi, Bridier, et al., 1997
6 CH2 rock 906 T gas LF Furubayashi, Bridier, et al., 1997
7 CC stretch 847 gas LF Furubayashi, Bridier, et al., 1997
8 FCO bend 584 gas LF Furubayashi, Bridier, et al., 1997
9 CCO bend 416 T gas LF Furubayashi, Bridier, et al., 1997

Additional references: Jacox, 1998, page 316; Jacox, 2003, page 321

Notes

TTentative assignment or approximate value
oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Furubayashi, Bridier, et al., 1997
Furubayashi, M.; Bridier, I.; Inomata, S.; Washinda, N.; Yamashita, K., Laser-induced fluorescence of the CH[sub 2]CFO radical, J. Chem. Phys., 1997, 106, 15, 6302, https://doi.org/10.1063/1.473641 . [all data]

Wright and Dagdigian, 1997
Wright, S.A.; Dagdigian, P.J., Rotational analysis of the B[sup 2]A[sup ´´]-X[sup 2]A[sup ´´] origin band of the CH[sub 2]CFO radical, J. Chem. Phys., 1997, 107, 23, 9755, https://doi.org/10.1063/1.475272 . [all data]

Yamaguchi, Furubayashi, et al., 1998
Yamaguchi, M.; Furubayashi, M.; Inomata, S.; Washida, N., Analysis of laser-induced fluorescence spectra of the transition with calculated Franck--Condon factors of CH2CFO, Chem. Phys. Lett., 1998, 298, 1-3, 93, https://doi.org/10.1016/S0009-2614(98)01188-9 . [all data]

Inomata, Furubayashi, et al., 1999
Inomata, S.; Furubayashi, M.; Imamura, T.; Washida, N.; Yamaguchi, M., Laser-induced fluorescence of the CD[sub 2]CFO radical, J. Chem. Phys., 1999, 111, 14, 6356, https://doi.org/10.1063/1.479961 . [all data]

Hoops, Gascooke, et al., 2004
Hoops, A.A.; Gascooke, J.R.; Kautzman, K.E.; Faulhaber, A.E.; Newmark, D.M., Photodissociation spectroscopy and dynamics of the CH[sub 2]CFO radical, J. Chem. Phys., 2004, 120, 18, 8494, https://doi.org/10.1063/1.1691016 . [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]


Notes

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