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BrNO2


Vibrational and/or electronic energy levels

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Tx = 50250 gas Scheffler, Grothe, et al., 1997

State:   ?


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Tx = 40490 gas Scheffler, Grothe, et al., 1997

State:   ?


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Tx = 26880 gas Scheffler, Grothe, et al., 1997

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 1 NO2 s-stretch 1294.40 gas IR Finlayson-Pitts, Livingston, et al., 1989
Frenzel, Scheer, et al., 1996
Scheffler, Grothe, et al., 1997
Orphal, 2000
1 NO2 s-stretch 1291.0 vs Ar IR Feuerhahn, Minkwitz, et al., 1979
Tevault, 1979
Scheffler, Grothe, et al., 1997
Scheffler and Willner, 1998
1 NO2 s-stretch 1291 O2 IR Frenzel, Scheer, et al., 1996
2 NO2 deform. 787.16 gas IR Finlayson-Pitts, Livingston, et al., 1989
Frenzel, Scheer, et al., 1996
Scheffler, Grothe, et al., 1997
Tchana, Orphal, et al., 2002
2 NO2 deform. 782.7 s Ar IR Tevault, 1979
Scheffler, Grothe, et al., 1997
Scheffler and Willner, 1998
2 NO2 deform. 784 O2 IR Frenzel, Scheer, et al., 1996
3 NBr stretch 281.8 w Ar IR Scheffler, Grothe, et al., 1997
Scheffler and Willner, 1998
3 NBr stretch 280.7 w Ar IR Scheffler, Grothe, et al., 1997
Scheffler and Willner, 1998
b1 4 OPLA 605 gas IR Scheffler, Grothe, et al., 1997
4 OPLA 605.7 Ar IR Scheffler, Grothe, et al., 1997
Scheffler and Willner, 1998
b2 5 NO2 a-stretch 1666.98 gas IR Finlayson-Pitts, Livingston, et al., 1989
Frenzel, Scheer, et al., 1996
Scheffler, Grothe, et al., 1997
Orphal, Frenzel, et al., 1998
5 NO2 a-stretch 1659.6 vs Ar IR Tevault, 1979
Scheffler, Grothe, et al., 1997
Scheffler and Willner, 1998
5 NO2 a-stretch 1655 O2 IR Frenzel, Scheer, et al., 1996
6 NO2 wag 290 T s Ar IR Scheffler, Grothe, et al., 1997

Additional references: Jacox, 1994, page 213; Jacox, 1998, page 260; Jacox, 2003, page 239

Notes

wWeak
sStrong
vsVery strong
TTentative assignment or approximate value
xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Scheffler, Grothe, et al., 1997
Scheffler, D.; Grothe, H.; Willner, H.; Frenzel, A.; Zetsch, C., Properties of Pure Nitryl Bromide. Thermal Behavior, UV/Vis and FTIR Spectra, and Photoisomerization to, Inorg. Chem., 1997, 36, 3, 335, https://doi.org/10.1021/ic9606946 . [all data]

Finlayson-Pitts, Livingston, et al., 1989
Finlayson-Pitts, B.J.; Livingston, F.E.; Berko, H.N., Synthesis and identification by infrared spectroscopy of gaseous nitryl bromide, BrNO2, J. Phys. Chem., 1989, 93, 11, 4397, https://doi.org/10.1021/j100348a005 . [all data]

Frenzel, Scheer, et al., 1996
Frenzel, A.; Scheer, V.; Behnke, W.; Zetsch, C., Synthesis and Mid-IR Absorption Cross Sections of BrNO, J. Phys. Chem., 1996, 100, 41, 16447, https://doi.org/10.1021/jp960319z . [all data]

Orphal, 2000
Orphal, J., The «nu»1 bands of 79BrNO2 and 81BrNO2, J. Mol. Struct., 2000, 517/518, 181, https://doi.org/10.1016/S0022-2860(99)00249-5 . [all data]

Feuerhahn, Minkwitz, et al., 1979
Feuerhahn, M.; Minkwitz, R.; Engelhardt, U., On the formation of nitryl bromide and nitryl iodide and the infrared spectra of the matrix isolated molecules, J. Mol. Spectrosc., 1979, 77, 3, 429, https://doi.org/10.1016/0022-2852(79)90182-6 . [all data]

Tevault, 1979
Tevault, D.E., Matrix reactions of bromine atoms and nitrogen dioxide molecules, J. Phys. Chem., 1979, 83, 17, 2217, https://doi.org/10.1021/j100480a007 . [all data]

Scheffler and Willner, 1998
Scheffler, D.; Willner, H., The Synthesis of, Inorg. Chem., 1998, 37, 18, 4500, https://doi.org/10.1021/ic9803006 . [all data]

Tchana, Orphal, et al., 2002
Tchana, F.K.; Orphal, J.; Kleiner, I.; Redlich, B.; Scheffler, D.; Mbiake, R.; Bouba, O., The «nu»2 Bands of BrNO2 around 787 cm-1 (12.7 «mu»m), J. Mol. Spectrosc., 2002, 216, 2, 292, https://doi.org/10.1006/jmsp.2002.8611 . [all data]

Orphal, Frenzel, et al., 1998
Orphal, J.; Frenzel, A.; Grothe, H.; Redlich, B.; Scheffler, D.; Willner, H.; Zetzsch, C., High-Resolution Infrared Fourier-Transform Spectroscopy and Rotational Constants of the «nu»4Band of BrNO2, J. Mol. Spectrosc., 1998, 191, 1, 88, https://doi.org/10.1006/jmsp.1998.7641 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]


Notes

Go To: Top, Vibrational and/or electronic energy levels, References