Manganese, tricarbonyl[(1,2,3,4,5-η)-1-methyl-2,4-cyclopentadien-1-yl]-

• Formula: C₉H₇MnO₃
• Molecular weight: 218.0881
• IUPAC Standard InChI: InChI=1S/C6H7.3CO.Mn/c1-6-4-2-3-5-6;3*1-2;/h2-5H,1H3;;;; Copy

  
• IUPAC Standard InChIKey: LYHJNAIHGFWRKM-UHFFFAOYSA-N Copy
• CAS Registry Number: 12108-13-3
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
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• Other names: Manganese, tricarbonyl(methyl-π-cyclopentadienyl)-; π-(Methylcyclopentadienyl)manganese tricarbonyl; (Methylcyclopentadienyl)manganese tricarbonyl; (Methylcyclopentadienyl)tricarbonylmanganese; Methylcymantrene; Tricarbonyl(methyl-π-cyclopentadienyl)manganese; Tricarbonyl(methylcyclopentadienyl)manganese; Tricarbonyl(2-methylcyclopentadienyl)manganese; 2-(Methylcyclopentadienyl)manganesetricarbonyl; (η5-Methylcyclopentadienyl) manganese tricarbonyl-; (1,2,3,4,5-η-1-Methyl-2,4-cyclopentadien-1-yl)manganese tricarbonyl; Manganese (methylcyclopentadienyl) tricarbonyl; Ak-33x; CI-2; Manganese, tricarbonyl methylcyclopentadienyl; Manganese, tricarbonyl(2-methylcyclopentadienyl)-; MMT; Antiknock-33; Combustion improver -2; Methylcyklopentadientrikarbonylmanganium; Manganese, tricarbonyl[(1,2,3,4,5-η)-1-methyl-2,4-cyclopentadie-1-yl]-; Manganese, tricarbonyl[(1,2,3,4,5-η5)-1-methyl-2,4-cyclopentadien-1-yl]-; NSC 22316
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• Information on this page:
  • Gas phase ion energetics data
  • References
  • Notes
• Other data available:
  • Mass spectrum (electron ionization)
• Data at other public NIST sites:
  • Gas Phase Kinetics Database
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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
B - John E. Bartmess

Electron affinity determinations

Ionization energy determinations

Appearance energy determinations

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]

Martel and Waller, 1998
Martel, A.A.; Waller, I.M., Negative-ion photoelectron spectrum of tricarbonyl(eta 5-methylcyclopentadienyl)manganate(0), J. Phys. Chem. A, 1998, 102, 50, 10258-10260, https://doi.org/10.1021/jp983333f . [all data]

Calabro and Lichtenberger, 1981
Calabro, D.C.; Lichtenberger, D.L., Valence ionizations of olefins coordinated to metals. Olefin dicarbonyl(η5-(methyl and pentamethyl)cyclopentadienyl)manganese complexes, J. Am. Chem. Soc., 1981, 103, 6846. [all data]

Guimon, Pfister-Guillouzo, et al., 1979
Guimon, C.; Pfister-Guillouzo, G.; Mathey, F., Electronic structure of phosphacymantrene by photoelectron spectroscopy (He I, He II) and E.H.T. calculations, Nouv. J. Chim., 1979, 3, 725. [all data]

Efraty, Huang, et al., 1975
Efraty, A.; Huang, M.H.A.; Weston, C.A., Mass spectra of organometallic compounds. V. Electron-impact study of the cyclopentadienylmanganese thiocarbonyl and carbonyl complexes RC₅H₄Mn(CO)₂CX [R=H, CH₃; X = S, O], Inorg. Chem., 1975, 14, 2796. [all data]

Calabro, Hubbard, et al., 1981
Calabro, D.C.; Hubbard, J.L.; Blevins, C.H., II; Campbell, A.C.; Lichtenberger, D.L., The effects of methyl group substitution on metal-coordinated cyclopentadienyl rings. The core and valence ionizations of methylated tricarbonyl(η5-cyclopentadienyl)metal complexes, J. Am. Chem. Soc., 1981, 103, 6839. [all data]

Notes

Go To: Top, Gas phase ion energetics data, References

• Symbols used in this document:
  

  AE	Appearance energy
  EA	Electron affinity

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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