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ClOO


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Tx = 40300 gas 225 270 Morris and Johnston, 1968
Johnston, Morris, et al., 1969
Baer, Hippler, et al., 1991
Mauldin, Burkholder, et al., 1992

State:   ?


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Tx = 40000 T Ne Muller and Willner, 1993

State:   ?


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Tx = 40000 T Ar Johnsson, Engdahl, et al., 1993

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 1 OO stretch 1443 gas IR Johnston, Morris, et al., 1969
1 OO stretch 1442.5 Ne IR Muller and Willner, 1993
Lai, Liu, et al., 1998
1 OO stretch 1439.6 Ne IR Muller and Willner, 1993
Lai, Liu, et al., 1998
1 OO stretch 1442.5 vs Ar IR Arkell and Schwager, 1967
Johnsson, Engdahl, et al., 1993
Lai, Liu, et al., 1998
1 OO stretch 1416.7 Ar IR Arkell and Schwager, 1967
Johnsson, Engdahl, et al., 1993
Lai, Liu, et al., 1998
1 OO stretch 1440.7 Kr IR Lai, Liu, et al., 1998
1 OO stretch 1412.1 Kr IR Lai, Liu, et al., 1998
1 OO stretch 1438 N2 IR Rochkind and Pimentel, 1967
1 OO stretch 1428 N2 IR Rochkind and Pimentel, 1967
1 OO stretch 1436 O2 IR Johnsson, Engdahl, et al., 1993
2 Bend 413.7 Ne IR Muller and Willner, 1993
2 Bend 408.3 w Ar IR Arkell and Schwager, 1967
Johnsson, Engdahl, et al., 1993
3 ClO stretch 201.4 Ne IR Muller and Willner, 1993
3 ClO stretch 192.4 w Ar IR Johnsson, Engdahl, et al., 1993
3 ClO stretch 203 O2 IR Johnsson, Engdahl, et al., 1993

Additional references: Jacox, 1994, page 110; Jacox, 1998, page 204; Jacox, 2003, page 147; Suma, Sumiyoshi, et al., 2004

Notes

wWeak
vsVery strong
TTentative assignment or approximate value
xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Morris and Johnston, 1968
Morris, E.D., Jr.; Johnston, H.S., Ultraviolet spectrum of the chlorine dioxygen radical, J. Am. Chem. Soc., 1968, 90, 7, 1918, https://doi.org/10.1021/ja01009a053 . [all data]

Johnston, Morris, et al., 1969
Johnston, H.S.; Morris, E.D., Jr.; Van den Bogaerde, J., Molecular Modulation Kinetic Spectrometry. CIOO and CIO, J. Am. Chem. Soc., 1969, 91, 27, 7712, https://doi.org/10.1021/ja50001a036 . [all data]

Baer, Hippler, et al., 1991
Baer, S.; Hippler, H.; Rahn, R.; Siefke, M.; Seitzinger, N.; Troe, J., Thermodynamic and kinetic properties of the reaction Cl+O2+M=ClOO+M in the range 160--300 K and 1--1000 bar, J. Chem. Phys., 1991, 95, 9, 6463, https://doi.org/10.1063/1.461543 . [all data]

Mauldin, Burkholder, et al., 1992
Mauldin, R.L., III; Burkholder, J.B.; Ravishankara, A.R., A photochemical, thermodynamic, and kinetic study of chloroperoxy, J. Phys. Chem., 1992, 96, 6, 2582, https://doi.org/10.1021/j100185a035 . [all data]

Muller and Willner, 1993
Muller, H.S.P.; Willner, H., Vibrational and electronic spectra of chlorine dioxide, OClO, and chlorine superoxide ClOO, isolated in cryogenic matrixes, J. Phys. Chem., 1993, 97, 41, 10589, https://doi.org/10.1021/j100143a013 . [all data]

Johnsson, Engdahl, et al., 1993
Johnsson, K.; Engdahl, A.; Nelander, B., A matrix isolation study of the chlorine superoxide radical, J. Phys. Chem., 1993, 97, 38, 9603, https://doi.org/10.1021/j100140a013 . [all data]

Lai, Liu, et al., 1998
Lai, L.-H.; Liu, C.-P.; Lee, Y.-P., Laser photolysis of OClO in solid Ne, Ar, and Kr. II. Site selectivity, mode specificity, and effects of matrix hosts, J. Chem. Phys., 1998, 109, 3, 988, https://doi.org/10.1063/1.476641 . [all data]

Arkell and Schwager, 1967
Arkell, A.; Schwager, I., None, J. Am. Chem. Soc., 1967, 89, 24, 5999, https://doi.org/10.1021/ja01000a001 . [all data]

Rochkind and Pimentel, 1967
Rochkind, M.M.; Pimentel, G.C., Photolysis of Matrix-Isolated Dichlorine Monoxide: Infrared Spectra of ClClO and (ClO)2, J. Chem. Phys., 1967, 46, 11, 4481, https://doi.org/10.1063/1.1840572 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Suma, Sumiyoshi, et al., 2004
Suma, K.; Sumiyoshi, Y.; Endo, Y., Fourier transform microwave spectroscopy and Fourier transform microwave--millimeter wave double resonance spectroscopy of the ClOO radical, J. Chem. Phys., 2004, 121, 17, 8351, https://doi.org/10.1063/1.1792591 . [all data]


Notes

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