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2,4-Pentanedione, 1,1,1,5,5,5-hexafluoro-

Data at NIST subscription sites:

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil343.KN/AFarchan Laboratories, 1990BS
Tboil343.KN/APCR Inc., 1990BS
Tboil343.2KN/AWeast and Grasselli, 1989BS
Tboil343.2KN/AMajer and Svoboda, 1985 
Quantity Value Units Method Reference Comment
Tc485.10KN/AMousa, 1981Uncertainty assigned by TRC = 1. K; TRC
Quantity Value Units Method Reference Comment
Pc28.6716barN/AMousa, 1981Uncertainty assigned by TRC = 0.08 bar; TRC
Quantity Value Units Method Reference Comment
Vc0.290l/molN/AMousa, 1981Uncertainty assigned by TRC = 0.008 l/mol; TRC
Quantity Value Units Method Reference Comment
Deltavap30.66kJ/molN/AMajer and Svoboda, 1985 
Deltavap30.6 ± 0.1kJ/molN/ARibeiro da Silva, Gonçalves, et al., 1997See also Irving and da Silva, 1975 and Ribeiro da Silva and Irving, 1978.; AC

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
27.05343.2N/AMajer and Svoboda, 1985 
33.1301.GSGeorge, Young, et al., 1998Based on data from 273. - 330. K.; AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Farchan Laboratories, 1990
Farchan Laboratories, Research Chemicals Catalog, Farchan Laboratories, Gainesville, FL, 1990, 91. [all data]

PCR Inc., 1990
PCR Inc., Research Chemicals Catalog 1990-1991, PCR Inc., Gainesville, FL, 1990, 1. [all data]

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Majer and Svoboda, 1985
Majer, V.; Svoboda, V., Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]

Mousa, 1981
Mousa, A.H.N., Critical constants, vapor pressure, and saturated volumes of hexafluoroacetylacetone., J. Chem. Eng. Data, 1981, 26, 248-9. [all data]

Ribeiro da Silva, Gonçalves, et al., 1997
Ribeiro da Silva, Manuel A.V.; Gonçalves, J.M.; Pilcher, G., Standard molar enthalpies of formation of nine fluorinated «beta»-diketones by rotating bomb calorimetry, The Journal of Chemical Thermodynamics, 1997, 29, 3, 253-260, https://doi.org/10.1006/jcht.1996.0143 . [all data]

Irving and da Silva, 1975
Irving, Roger J.; da Silva, Manuel A.V. Ribeiro, Enthalpies of vaporization of some ?-diketones, J. Chem. Soc., Dalton Trans., 1975, 9, 798, https://doi.org/10.1039/dt9750000798 . [all data]

Ribeiro da Silva and Irving, 1978
Ribeiro da Silva, M.A.V.; Irving, R.G., Rev. Port. Quim., 1978, 20, 36. [all data]

George, Young, et al., 1998
George, Mark A.; Young, Kris M.; Robertson, Eric A.; Beck, Scott E.; Voloshin, George, Vapor Pressure and Viscosity of 1,1,1,5,5,5-Hexafluoro-2,4-pentanedione, J. Chem. Eng. Data, 1998, 43, 1, 60-64, https://doi.org/10.1021/je9700941 . [all data]


Notes

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