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NO2+


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   D


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 75485 gas Jarvis, Song, et al., 1999


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 1 Sym. stretch 1102 gas TPE Jarvis, Song, et al., 1999

State:   e


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 74799 gas Brundle, Neumann, et al., 1970
Edqvist, Lindholm, et al., 1970
Baltzer, Karlsson, et al., 1998
Jarvis, Song, et al., 1999


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 1 Sym. stretch 1114 gas PE TPE Brundle, Neumann, et al., 1970
Edqvist, Lindholm, et al., 1970
Baltzer, Karlsson, et al., 1998
Jarvis, Song, et al., 1999

State:   d


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 71622 gas Jarvis, Song, et al., 1999


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 1 Sym. stretch 1402 gas TPE Jarvis, Song, et al., 1999
2 Bend 941 gas TPE Jarvis, Song, et al., 1999
b2 3 Asym. stretch 2054 gas TPE Jarvis, Song, et al., 1999

State:   C


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 60902 gas Edqvist, Lindholm, et al., 1970
Baltzer, Karlsson, et al., 1998
Jarvis, Song, et al., 1999


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 1 Sym. stretch 1009 gas PE TPE Brundle, Neumann, et al., 1970
Edqvist, Lindholm, et al., 1970
Baltzer, Karlsson, et al., 1998
Jarvis, Song, et al., 1999

State:   c


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 60354 gas Brundle, Neumann, et al., 1970
Edqvist, Lindholm, et al., 1970
Baltzer, Karlsson, et al., 1998
Jarvis, Song, et al., 1999


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 1 Sym. stretch 1024 gas PE TPE Brundle, Neumann, et al., 1970
Edqvist, Lindholm, et al., 1970
Baltzer, Karlsson, et al., 1998
Jarvis, Song, et al., 1999

State:   B


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 39166 gas Brundle, Neumann, et al., 1970
Edqvist, Lindholm, et al., 1970
Baltzer, Karlsson, et al., 1998
Jarvis, Song, et al., 1999


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 1 Sym. stretch 1038 gas PE TPE Edqvist, Lindholm, et al., 1970
Baltzer, Karlsson, et al., 1998
Jarvis, Song, et al., 1999
2 Bend 576 gas PE TPE Brundle, Neumann, et al., 1970
Edqvist, Lindholm, et al., 1970
Baltzer, Karlsson, et al., 1998
Jarvis, Song, et al., 1999
b2 3 Asym. stretch 1495 gas TPE Jarvis, Song, et al., 1999

State:   A


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 36150 gas Brundle, Neumann, et al., 1970
Edqvist, Lindholm, et al., 1970
Baltzer, Karlsson, et al., 1998
Jarvis, Song, et al., 1999


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 1 Sym. stretch 963 gas PE TPE Brundle, Neumann, et al., 1970
Edqvist, Lindholm, et al., 1970
Baltzer, Karlsson, et al., 1998
Jarvis, Song, et al., 1999
2 Bend 615 gas TPE Jarvis, Song, et al., 1999

State:   b


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 32318 gas Brundle, Neumann, et al., 1970
Edqvist, Lindholm, et al., 1970
Baltzer, Karlsson, et al., 1998
Jarvis, Song, et al., 1999


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 2 Bend 685 gas PE TPE Brundle, Neumann, et al., 1970
Edqvist, Lindholm, et al., 1970
Baltzer, Karlsson, et al., 1998
Jarvis, Song, et al., 1999

State:   a


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 26422 gas Brundle, Neumann, et al., 1970
Edqvist, Lindholm, et al., 1970
Baltzer, Karlsson, et al., 1998
Jarvis, Song, et al., 1999


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 2 Bend 639 gas PE TPE Brundle, Neumann, et al., 1970
Edqvist, Lindholm, et al., 1970
Baltzer, Karlsson, et al., 1998
Jarvis, Song, et al., 1999

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

Sigmag+ 1 Sym. stretch 1401.1 gas TPE Matsui, Behm, et al., 1996
Matsui, Behm, et al., 1997
Jarvis, Song, et al., 1999
1 Sym. stretch 1362.4 T Ne IR Forney, Thompson, et al., 1993
Pi 2 Bend 627.7 gas TPE Bryant, Jiang, et al., 1992
Bryant, Jiang, et al., 1994
Matsui, Behm, et al., 1996
Matsui, Behm, et al., 1997
Jarvis, Song, et al., 1999
Sigmau+ 3 Asym. stretch 2376.5 gas TPE Bryant, Jiang, et al., 1992
Bryant, Jiang, et al., 1994
Jarvis, Song, et al., 1999
3 Asym. stretch 2348.2 Ne IR Forney, Thompson, et al., 1993

Additional references: Jacox, 1994, page 87; Jacox, 1998, page 190; Jacox, 2003, page 132; Killgoar, Leroi, et al., 1973; Bryant, Jiang, et al., 1992, 2

Notes

TTentative assignment or approximate value
oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Jarvis, Song, et al., 1999
Jarvis, G.K.; Song, Y.; Ng, C.Y.; Grant, E.R., A characterization of vibrationally and electronically excited NO[sub 2][sup +] by high-resolution threshold photoionization spectroscopy, J. Chem. Phys., 1999, 111, 21, 9568, https://doi.org/10.1063/1.480288 . [all data]

Brundle, Neumann, et al., 1970
Brundle, C.R.; Neumann, D.; Price, W.C.; Evans, D.; Potts, A.W.; Streets, D.G., Electronic structure of NO, studied by photoelectron and vacuum-uv spectroscopy and Gaussian orbital calculations, J. Chem. Phys., 1970, 53, 705. [all data]

Edqvist, Lindholm, et al., 1970
Edqvist, O.; Lindholm, E.; Selin, L.E.; Asbrink, L., Phys. Scripta, 1970, 1, 127. [all data]

Baltzer, Karlsson, et al., 1998
Baltzer, P.; Karlsson, L.; Wannberg, B.; Holland, D.M.P.; MacDonald, M.A.; Hayes, M.A.; Eland, J.H.D., An experimental study of the valence shell photoelectron spectrum of the NO2 molecule, Chem. Phys., 1998, 237, 3, 451, https://doi.org/10.1016/S0301-0104(98)00240-7 . [all data]

Matsui, Behm, et al., 1996
Matsui, H.; Behm, J.M.; Grant, E.R., Bend-stretch Fermi resonance in NO2+ observed by delayed pulsed-field ionization zero-electron kinetic energy photoelectron spectroscopy, Int. J. Mass Spectrom. Ion Proc., 1996, 159, 1-3, 37, https://doi.org/10.1016/S0168-1176(96)04440-0 . [all data]

Matsui, Behm, et al., 1997
Matsui, H.; Behm, J.M.; Grant, E.R., Photoselection and the Appearance of Franck-Condon-Forbidden Thresholds in the ZEKE Spectrum of NO, J. Phys. Chem. A, 1997, 101, 36, 6717, https://doi.org/10.1021/jp970556h . [all data]

Forney, Thompson, et al., 1993
Forney, D.; Thompson, W.E.; Jacox, M.E., The vibrational spectra of molecular ions isolated in solid neon. XI. NO+2, NO-2, and NO-3, J. Chem. Phys., 1993, 99, 10, 7393, https://doi.org/10.1063/1.465720 . [all data]

Bryant, Jiang, et al., 1992
Bryant, G.; Jiang, Y.; Grant, E., The vibrational structure of the NO2 cation, Chem. Phys. Lett., 1992, 200, 5, 495, https://doi.org/10.1016/0009-2614(92)80081-L . [all data]

Bryant, Jiang, et al., 1994
Bryant, G.P.; Jiang, Y.; Martin, M.; Grant, E.R., Rovibrational structure of NO+2 and state-to-state dynamics in the high-resolution threshold photoionization of NO2, J. Chem. Phys., 1994, 101, 9, 7199, https://doi.org/10.1063/1.468277 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Killgoar, Leroi, et al., 1973
Killgoar, P.C., Jr.; Leroi, G.E.; Chupka, W.A.; Berkowitz, J., Photoionization study of NO2. I. The ionization potential, J. Chem. Phys., 1973, 59, 1370. [all data]

Bryant, Jiang, et al., 1992, 2
Bryant, G.P.; Jiang, Y.; Martin, M.; Grant, E.R., Structured effects of Rydberg-Rydberg rotational coupling on intensities in the zero electron kinetic energy threshold photoionization spectrum of state-selected nitrogen dioxide, J. Phys. Chem., 1992, 96, 17, 6875, https://doi.org/10.1021/j100196a008 . [all data]


Notes

Go To: Top, Vibrational and/or electronic energy levels, References