4-Fluorobenzyl radical

• Formula: C₇H₆F
• Molecular weight: 109.1209
• IUPAC Standard InChI: InChI=1S/C7H6F/c1-6-2-4-7(8)5-3-6/h2-5H,1H2 Copy

  
• IUPAC Standard InChIKey: GVVVXNGTIKFYKV-UHFFFAOYSA-N Copy
• CAS Registry Number: 2194-09-4
• Chemical structure:
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• Information on this page:
  • Gas phase ion energetics data
  • Vibrational and/or electronic energy levels
  • References
  • Notes
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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

View reactions leading to C₇H₆F⁺ (ion structure unspecified)

Electron affinity determinations

Ionization energy determinations

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   A

State:   X

Additional references: Jacox, 1998, page 370; Jacox, 2003, page 402; Baek and Lee, 1998

Notes

References

Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, NIST Free Links, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kim, Wenthold, et al., 1999
Kim, J.B.; Wenthold, P.G.; Lineberger, W.C., Ultraviolet photoelectron spectroscopy of o-, m-, and p-halobenzyl anions, J. Phys. Chem. A, 1999, 103, 50, 10833-10841, https://doi.org/10.1021/jp992817o . [all data]

Harrison, Kebarle, et al., 1961
Harrison, A.G.; Kebarle, P.; Lossing, F.P., Free radicals by mass spectrometry. XXI. The ionization potentials of some meta and para substituted benzyl radicals, J. Am. Chem. Soc., 1961, 83, 777. [all data]

Bindley, Watts, et al., 1964
Bindley, T.F.; Watts, A.T.; Walker, S., Electronic emission spectra of radicals from fluorotoluenes, Trans. Faraday Soc., 1964, 60, 1, https://doi.org/10.1039/tf9646000001 . [all data]

Charlton and Thrush, 1986
Charlton, T.R.; Thrush, B.A., The study of substituted benzyl radicals by laser-induced fluorescence, Chem. Phys. Lett., 1986, 125, 5-6, 547, https://doi.org/10.1016/0009-2614(86)87096-8 . [all data]

Cossart-Magos and Cossart, 1988
Cossart-Magos, C.; Cossart, D., Rotational band contours of the first electronic transition origin bands of p-xylyl and p-fluorobenzyl, Mol. Phys., 1988, 65, 3, 627, https://doi.org/10.1080/00268978800101291 . [all data]

Fukushima and Obi, 1990
Fukushima, M.; Obi, K., Jet spectroscopy and excited state dynamics of benzyl and substituted benzyl radicals, J. Chem. Phys., 1990, 93, 12, 8488, https://doi.org/10.1063/1.459710 . [all data]

Lee and Baek, 1999
Lee, S.K.; Baek, D.Y., Vibronic analysis of the jet-cooled emission spectrum of p-fluorobenzyl radical in the D1→D0 transition, Chem. Phys. Lett., 1999, 301, 3-4, 407, https://doi.org/10.1016/S0009-2614(98)01436-5 . [all data]

Kim, Wenthold, et al., 1999, 2
Kim, J.B.; Wenthold, P.G.; Lineberger, W.C., Ultraviolet Photoelectron Spectroscopy of, J. Phys. Chem. A, 1999, 103, 50, 10833, https://doi.org/10.1021/jp992817o . [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Baek and Lee, 1998
Baek, D.Y.; Lee, S.K., Bull. Korean Chem. Soc., 1998, 19, 1359. [all data]

Notes

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• Symbols used in this document:
  

  EA	Electron affinity

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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