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LiCH3


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 1 CH3 s-stretch 2780 Ar IR Andrews, 1967
2 CH3 umbrella 1158 Ar IR Andrews, 1967
3 CLi stretch 530 T Ar IR Andrews, 1967
e 4 CH3 a-stretch 2820 Ar IR Andrews, 1967
5 CH3 deformation 1387 Ar IR Andrews, 1967
6 HCLi deform. 408.5 Ar IR Andrews, 1967

Additional references: Jacox, 2003, page 247; Grotjahn, Pesch, et al., 1997; Allen, Pesch, et al., 1998; Grotjahn, Pesch, et al., 2000

Notes

TTentative assignment or approximate value

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Andrews, 1967
Andrews, L., Infrared Spectrum of Methyl Lithium Monomer in Solid Argon, J. Chem. Phys., 1967, 47, 11, 4834, https://doi.org/10.1063/1.1701708 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Grotjahn, Pesch, et al., 1997
Grotjahn, D.B.; Pesch, T.C.; Xin, J.; Ziurys, L.M., Structure of Solvent-Free, Monomeric CH, J. Am. Chem. Soc., 1997, 119, 50, 12368, https://doi.org/10.1021/ja972613q . [all data]

Allen, Pesch, et al., 1998
Allen, M.D.; Pesch, T.C.; Robinson, J.S.; Apponi, A.J.; Grotjahn, D.B.; Ziurys, L.M., The pure rotational spectrum of LiCH3(), Chem. Phys. Lett., 1998, 293, 5-6, 397, https://doi.org/10.1016/S0009-2614(98)00810-0 . [all data]

Grotjahn, Pesch, et al., 2000
Grotjahn, D.B.; Pesch, T.C.; Brewster, M.A.; Ziurys, L.M., Synthesis of CH, J. Am. Chem. Soc., 2000, 122, 19, 4735, https://doi.org/10.1021/ja993136+ . [all data]


Notes

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